Isolongifolene

Isolongifolene
  • CAS No.:1135-66-6
Other grades of this product :
Isolongifolene Basic information
Product Name:Isolongifolene
Synonyms:(-)-Isolongifolene >=98.0% (suM of enantioMers, GC);(-)-Isolongifoline;(2s)-1,3,4,5,6,7-hexahydro-1,1,5,5;(2s)-1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-2h-2,4a-methanonaphthalene;2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-;C15 H24, 2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S)-;ISOLONGIFOLENE(SG);(2s)-2h-1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-4a-methanonaphthalen
CAS:1135-66-6
MF:C15H24
MW:204.35
EINECS:214-494-2
Product Categories:
Mol File:1135-66-6.mol
Isolongifolene Chemical Properties
Boiling point 255-256 °C
density 0.930 g/mL at 20 °C(lit.)
vapor pressure 5.49Pa at 25℃
refractive index n20/D 1.499
Fp 49°C
storage temp. 2-8°C
optical activity[α]20/D 138±2°, c = 1% in ethanol
Water Solubility 59.998μg/L at 25℃
BRN 2207559
LogP5.77 at 25℃
CAS DataBase Reference1135-66-6(CAS DataBase Reference)
NIST Chemistry Reference2H-2,4a-methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2s)-(1135-66-6)
EPA Substance Registry System2H-2,4a-Methanonaphthalene, 1,3,4,5,6,7-hexahydro-1,1,5,5-tetramethyl-, (2S,4aR)- (1135-66-6)
Safety Information
Risk Statements 10
RIDADR UN 2319 3/PG 3
WGK Germany 3
HazardClass 3.2
PackingGroup III
MSDS Information
ProviderLanguage
SigmaAldrich English
Isolongifolene Usage And Synthesis
Uses(-)-Isolongifolene may be used in the preparation of (-)-isolongifolenone, a potent insect repellent.
General Description(-)-Isolongifolene is a sesquiterpene that can be found in pine cone and Japanese cedar essential oils.
Flammability and ExplosibilityFlammable
Purification MethodsReflux it over, and distil it from Na. [Zeiss & Arakawa J Am Chem Soc 76 1653 1954, IR: Reinaecker & Graafe Angew Chem, Int Ed Engl 97 348 1985, UV and NMR: Ranganathan et al. Tetrahedron 26 621 1970, Beilstein 5 IV 1191.]
Isolongifolene Preparation Products And Raw materials

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