Product

Chlorobis(cyclooctene)rhodium(I) dimer

CAS No.：12279-09-3

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Chlorobis(cyclooctene)rhodium(I) dimer Basic information

Product Name:	Chlorobis(cyclooctene)rhodium(I) dimer
Synonyms:	[RhCl(cis-cyclooctene)2]2;CHLOROBIS(CYCLOOCTENE)RHODIUM(I) DIMER;Chlorobis(cyclooctene)rhodium(I);Chlorobis(cyclooctene)rhodium(I)dimere;Chlorobis(cyclooctene)rhodium(I)dimer,min.98%;Chlorobis(cyclooctene)rhodium(I) dimer, min. 98%;Chlorobis(cyclooctene)rhodium(I) dimer,98%;CHLOROBIS(CYCLOOCTENE)RHODIUM()DIMER
CAS:	12279-09-3
MF:	C32H56Cl2Rh2
MW:	717.5
EINECS:	623-340-7
Product Categories:	Rh;organometallic complex;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Rh (Rhodium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;Catalysis and Inorganic Chemistry;Chemical Synthesis;Rhodium
Mol File:	12279-09-3.mol

Chlorobis(cyclooctene)rhodium(I) dimer Chemical Properties

Melting point	190 °C (dec.) (lit.)
storage temp.	Freezer
form	crystal
color	orange to red
Sensitive	air sensitive, store cold
CAS DataBase Reference	12279-09-3

Safety Information

Hazard Codes	Xn
Risk Statements	20/21/22-36/37/38
Safety Statements	26-37/39
WGK Germany	3
TSCA	No
HS Code	28439000

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

Chlorobis(cyclooctene)rhodium(I) dimer Usage And Synthesis

Chemical Properties	orange-brown powder
Uses	Chlorobis(cyclooctene)rhodium(I),dimer can be used as a catalyst: To synthesize enantioenriched gem-diaryl sulfonates by asymmetric 1,4-addition of aryl boronic acids to α,β-unsaturated sulfonyl compounds. In direct C-arylation of N-unprotected indoles and pyrroles. In the carboxylation of arenes via C-H bond activation.
Uses	Chlorobis(cyclooctene)rhodium(I) dimer is an organometallic complex used as a catalyst in the arylzincation of alkynes. It is also used as a building block for other Rh-based catalysts, such as the preparation of rhodium bis(phosphinimine)pyrrole pincer carbonyl complexes for deoxygenative metathesis of CO.

Chlorobis(cyclooctene)rhodium(I) dimer Preparation Products And Raw materials

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