1,3-Dichloropropane

1,3-Dichloropropane
  • CAS No.:142-28-9
Other grades of this product :
1,3-Dichloropropane Basic information
Product Name:1,3-Dichloropropane
Synonyms:1,3-DICHLOROPROPANE;propane,1,3-dichloro;Propane,1,3-dichloro-;r270fa;1,3-dichloropropane solution;propylendichloride;1,3-Dichloropropane (1mg/ml in Methanol) [for Water Analysis];Dichloropropane, 1,3-
CAS:142-28-9
MF:C3H6Cl2
MW:112.99
EINECS:205-531-3
Product Categories:Alpha Sort;D;alpha,omega-Bifunctional Alkanes;DAlphabetic;DIA - DIC;Volatiles/ Semivolatiles;alpha,omega-Dichloroalkanes;Monofunctional & alpha,omega-Bifunctional Alkanes;Analytical Chemistry;Standard Solution of Volatile Organic Compounds for Water & Soil Analysis;Standard Solutions (VOC)
Mol File:142-28-9.mol
1,3-Dichloropropane Chemical Properties
Melting point −99 °C(lit.)
Boiling point 120-122 °C(lit.)
density 1.19 g/mL at 25 °C(lit.)
vapor pressure 24-24.265hPa at 20-25℃
refractive index n20/D 1.448(lit.)
Fp 90 °F
storage temp. Refrigerator
form Liquid
color Clear colorless
Water Solubility 0.8 g/L (20 ºC)
BRN 505960
InChIKeyYHRUOJUYPBUZOS-UHFFFAOYSA-N
LogP2 at 25℃ and pH7
CAS DataBase Reference142-28-9(CAS DataBase Reference)
NIST Chemistry ReferencePropane, 1,3-dichloro-(142-28-9)
EPA Substance Registry System1,3-Dichloropropane (142-28-9)
Safety Information
Hazard Codes F,Xn,T,Xi
Risk Statements 11-20-20/22-52/53-36/37/38-39/23/24/25-23/24/25-36-20/21/22
Safety Statements 9-16-29-33-24-61-26-45-36/37-7
RIDADR UN 1993 3/PG 2
WGK Germany 2
RTECS TX9660000
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29031990
Hazardous Substances Data142-28-9(Hazardous Substances Data)
MSDS Information
ProviderLanguage
1,3-Dichloropropane English
ACROS English
SigmaAldrich English
ALFA English
1,3-Dichloropropane Usage And Synthesis
Chemical Properties1,3-Dichloropropene occurs as a clear colourless liquid with a sweet chloroform-like odor. It is soluble in alcohol and ether, dissolves in water (0.27g/100ml). The half-life of 1,3-dichloropropene in ambient air may range from 7 to 50 hours.
Uses1,3-Dichloropropane is used as an intermediate in organic synthesis. It is also used as solvent, detergent and chromatographic analysis. Further, it is used to prepare 3,7-dithia-nonanedioic acid by reacting with mercaptoacetic acid.
DefinitionChEBI: 1,3-dichloropropane is a chloroalkane that is propane in which a hydrogen from each of the terminal methyl groups has been replaced by a chlorine. It has a role as an environmental contaminant and a nematicide. It is a chloroalkane and a chlorohydrocarbon.
Preparation1,3-Dichloropropane is obtained by the action of propylene glycol with hydrochloric acid.1,3-Dichloropropane synthesis: A process for the preparation of 1,3-dichloropropane by reacting bis(3-hydroxypropyl)ether with hydrogen chloride, optionally in the presence of tertiary basic nitrogen compounds or other tertiary aliphatic bases as catalysts, distilling off the 1,3-dichloropropane and the water of reaction and working up the two phases. Process for the preparation of 1,3-dichloropropane
Synthesis Reference(s)The Journal of Organic Chemistry, 29, p. 194, 1964 DOI: 10.1021/jo01024a045
General Description1,3-dichloropropane is a colorless watery liquid with a sweet odor. Sinks in water. Produces irritating vapor. (USCG, 1999)
Air & Water ReactionsHighly flammable.
Reactivity ProfileHalogenated aliphatic compounds, such as 1,3-Dichloropropane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides.
Health HazardINHALATION: May cause some central nervous system depression. EYES: May cause some pain and irritation. SKIN: Mild irritation.
Safety ProfileModerately toxic by ingestion. Mutation data reported. A very dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits highly toxic fumes of Cl and phosgene. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and PROPYLENE DICHLORIDE.

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