1-Bromo-2-methylpropane

1-Bromo-2-methylpropane
  • CAS No.:78-77-3
Other grades of this product :
1-Bromo-2-methylpropane Basic information
Product Name:1-Bromo-2-methylpropane
Synonyms:1-BROMO-2-METHYLPROPANE;ISOBUTYL BROMIDE;1-bromo-2-methyl-propan;1-Bromo-iso-butame;2-Methylpropylbromide;bromoisobutane;i-Butyl bromide;Isobutylbromid
CAS:78-77-3
MF:C4H9Br
MW:137.02
EINECS:201-141-2
Product Categories:Organics;ALKYL BROMIDE
Mol File:78-77-3.mol
1-Bromo-2-methylpropane Chemical Properties
Melting point -119 °C
Boiling point 90-92 °C(lit.)
density 1.26 g/mL at 20 °C(lit.)
vapor pressure 41 hPa (20 °C)
refractive index n20/D 1.435(lit.)
Fp 65 °F
storage temp. Store below +30°C.
solubility 0.51g/l slightly soluble
form Liquid
color Clear colorless
Water Solubility 0.51 g/L (18 ºC)
Merck 14,5135
BRN 1730915
InChIKeyHLVFKOKELQSXIQ-UHFFFAOYSA-N
CAS DataBase Reference78-77-3(CAS DataBase Reference)
NIST Chemistry ReferencePropane, 1-bromo-2-methyl-(78-77-3)
EPA Substance Registry SystemPropane, 1-bromo-2-methyl- (78-77-3)
Safety Information
Hazard Codes F,Xi
Risk Statements 11-37-36/37/38
Safety Statements 16-23-37/39-26
RIDADR UN 2342 3/PG 2
WGK Germany 3
RTECS TX4140000
8
TSCA Yes
HazardClass 3
PackingGroup II
HS Code 29033036
ToxicityLD50 orally in Rabbit: > 2000 mg/kg
MSDS Information
ProviderLanguage
Isobutyl bromide English
SigmaAldrich English
ACROS English
ALFA English
1-Bromo-2-methylpropane Usage And Synthesis
Chemical PropertiesCLEAR LIQUID
Uses1-Bromo-2-methylpropane is used as a synthetic reagent for the preparation of 1-ethyl-1,3-isobutylimidazolium bromide by reaction with 1-ethylimidazole.
Safety ProfileQuestionable carcinogen with experimental neoplastigenic data. Moderately toxic by intraperitoneal route. A dangerous fire hazard when exposed to heat or flame. When heated to decomposition it emits toxic fumes of Br-. See also BROMIDES.
Purification MethodsPartially hydrolyse it to remove any tertiary alkyl halide, then fractionally distil it, then wash it with conc H2SO4, water and aqueous K2CO3, then redistil it from dry K2CO3. [Dunbar & Hammett J Am Chem Soc 72 109 1950, Beilstein 1 IV 294.]

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