DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)

DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
  • CAS No.:132071-87-5
Other grades of this product :
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Basic information
Reaction
Product Name:DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II)
Synonyms:Dichloro〔(R)-(+)-2,2-bis(diphenylphosphino)-1,1-binaphthyl)ruthenium(Ⅱ);Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1, 1'-binaphthyl]ruthenium(II), min. 95%;Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II),98% [(R)-BINAP]RuCl2;[(R)-BINAP]RUCL2;(R)-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl]dichlororuthenium(II);[(R)-(+)-2,2'-Bis-(diphenylphosphino)-1,1'-binaphthyl] ruthenium dichloride;Dichloro[(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]rutheniuM(II),95% [(R)-BINAP]RuCl2;Dichloro [(R)-(+)-2,2'-bis(diphenylphosphino)-1,1'-binaphathyl] rutheniuM(II)
CAS:132071-87-5
MF:C44H32Cl2P2Ru
MW:794.65
EINECS:623-973-9
Product Categories:Ru;Catalysts for Organic Synthesis;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:132071-87-5.mol
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Chemical Properties
Melting point >300 ºC
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Powder
color orange
Sensitive air sensitive
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36/37/39-36/37
MSDS Information
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Usage And Synthesis
Reaction
  1. Enantioselective catalyst for the asymmetric hydrogenation of α,β-unsaturated olefins.
  2. Efficient catalyst for the asymmetric reduction of carbonyl groups, such as β-ketoesters.
Uses(R)?-?[2,?2''-?Bis(diphenylphosphin?o)?-?1,?1''-?binaphthyl]?dichlororuthenium is a catalyst used in the synthesis of helicobacter pylori lipopolysaccharide structures displaying anti-inflammatory activiy.
DICHLORO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM (II) Preparation Products And Raw materials

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