Product

4-Nitrophenylboronic acid

CAS No.：24067-17-2

Other grades of this product :

4-Nitrophenylboronic acid Basic information

Product Name:	4-Nitrophenylboronic acid
Synonyms:	4-NITROPHENYLBORONIC ACID;4-NITROBENZENEBORONIC ACID;RARECHEM AH PB 0141;P-NITROPHENYLBORONIC ACID;4-Nitrophenylboronic Acid (contains varying amounts of Anhydride);4-Nitrophenylboronic acid ,97%;4-Borononitrobenzene;Boronic acid, B-(4-nitrophenyl)-
CAS:	24067-17-2
MF:	C6H6BNO4
MW:	166.93
EINECS:	627-647-7
Product Categories:	Boronate Ester;Boronic Acid;blocks;BoronicAcids;B (Classes of Boron Compounds);Potassium Trifluoroborate;Substituted Boronic Acids;Boronic acids;Aryl;Boronic Acids;Boronic Acids and Derivatives
Mol File:	24067-17-2.mol

4-Nitrophenylboronic acid Chemical Properties

Melting point	285-290°C (dec.)
Boiling point	373.7±44.0 °C(Predicted)
density	1.40±0.1 g/cm3(Predicted)
storage temp.	Inert atmosphere,Room Temperature
pka	7.04±0.10(Predicted)
form	Crystalline Powder
color	White to yellow
Water Solubility	Slightly soluble in water.
InChIKey	NSFJAFZHYOAMHL-UHFFFAOYSA-N
CAS DataBase Reference	24067-17-2(CAS DataBase Reference)

Safety Information

Hazard Codes	Xn
Risk Statements	22
Safety Statements	26-36/37/39-24/25
WGK Germany	3
Hazard Note	Harmful
HS Code	29319090

MSDS Information

4-Nitrophenylboronic acid Usage And Synthesis

Description	4-Nitrobenzeneboronic acid is an arylboronic acid building block that has been used in the synthesis of phenols.
Chemical Properties	White to brown powder or crystal
Uses	4-Nitrophenylboronic Acid is a useful synthetic intermediate. It is a reagent used for ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings, Ruthenium catalyzed direct arylation of benzylic sp3 carbons of acyclic amines and Diels-Alder or C-H activation reactions.
Uses	Reagent used for Ligand-free palladium-catalyzed Suzuki-Miyaura cross-couplings Ruthenium catalyzed direct arylation of benzylic sp³ carbons of acyclic amines Diels-Alder or C-H activation reactions Regioselective Suzuki-Miyaura coupling and tandem palladium-catalyzed intramolecular aminocarbonylation and annulations N-arylation of phenylurea using copper acetylacetonate catalyst Environmentally benign one-pot synthesis through a double arylation process Copper-mediated cyanations copper-catalyzed arylations Regioselective glycosylations Suzuki couplings followed by arylations X-ray absorption on rhodium-grafted hydrotalcite catalyst for heterogeneous 1,4-addition reaction of organoboron reagents to electron deficient olefins Reagent used in Preparation of Combretastatin analogs as potential antitumor agents Human immunodeficiency virus (HIV) protease inhibitors with antiviral activities against drug-resistant viruses
Uses	suzuki reaction

4-Nitrophenylboronic acid Preparation Products And Raw materials

Raw materials	Hydrochloric acid-->Tetrahydrofuran-->Toluene-->n-Butyllithium-->Triisopropyl borate-->Cuprous iodide-->Potassium Acetate-->Sodium periodate-->[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)-->Bis(pinacolato)diboron-->1-Bromo-4-nitrobenzene-->1-Iodo-4-nitrobenzene
Preparation Products	4-Nitrophenylboronic acid pinacol ester-->4-Nitrobiphenyl-->5-(4-NITRO-PHENYL)-2H-TETRAZOLE

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