3-(Trifluoromethyl)benzyl bromide

CAS No.：402-23-3

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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3-(Trifluoromethyl)benzyl bromide Basic information

Product Name:	3-(Trifluoromethyl)benzyl bromide
Synonyms:	3-(Bromomethyl)benzotrifluoride, 1-(Bromomethyl)-3-(trifluoromethyl)benzene;ALPHA'-BROMO-ALPHA,ALPHA,ALPHA-TRIFLUORO-M-XYLENE;ALPHA-BROMO-ALPHA',ALPHA',ALPHA'-TRIFLUORO-M-XYLENE;A'-BROMO-A,A,A-TRIFLUORO-M-XYLENE;3-(TRIFLUOROMETHYL)BENZYL BROMIDE;3-(BROMOMETHYL)BENZOTRIFLUORIDE;3-(TrifluoroMethyl)broMide;3-(Bromomethyl)benzotrifluoride alpha-Bromo-alpha',alpha',alpha'-trifluoro-m-xylene
CAS:	402-23-3
MF:	C8H6BrF3
MW:	239.03
EINECS:	206-938-9
Product Categories:	Aromatic Halides (substituted);Miscellaneous;Fluoro-contained benzyl bromide series;Benzenes;Benzyl;Aromatics;Miscellaneous Reagents;Halogenated Heterocycles ,Pyrimidines
Mol File:	402-23-3.mol

3-(Trifluoromethyl)benzyl bromide Chemical Properties

Boiling point	69 °C/4 mmHg (lit.)
density	1.565 g/mL at 25 °C (lit.)
refractive index	n20/D 1.492(lit.)
Fp	190 °F
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	clear liquid
Specific Gravity	1.565
color	Colorless to Almost colorless
Sensitive	Lachrymatory
BRN	743243
CAS DataBase Reference	402-23-3(CAS DataBase Reference)
NIST Chemistry Reference	3-Trifluoromethylbenzyl bromide(402-23-3)

Safety Information

Hazard Codes	C,Xi
Risk Statements	34
Safety Statements	26-36/37/39-45-25
RIDADR	UN 3265 8/PG 2
WGK Germany	3
Hazard Note	Corrosive/Lachrymatory
HazardClass	8
PackingGroup	III
HS Code	29039990

MSDS Information

Provider	Language
3-(Trifluoromethyl)benzyl bromide	English
SigmaAldrich	English
ACROS	English
ALFA	English

3-(Trifluoromethyl)benzyl bromide Usage And Synthesis

Chemical Properties	Colorless to light yellow liqui
Uses	Used in the preparation of 1-benzylazetidine-3-carboxylic acid derivatives as agonists and antagonists of the S1P5 receptor.
Uses	3-(Trifluoromethyl)benzyl bromide has been used in the preparation of flocoumafen.

3-(Trifluoromethyl)benzyl bromide Preparation Products And Raw materials

Raw materials	(3-(Trifluoromethyl)phenyl)magnesium bromide, 0.25 M in THF-->3-METHYLBENZOTRIFLUORIDE-->3-(Trifluoromethyl)benzyl alcohol-->3-(Trifluoromethyl)benzaldehyde
Preparation Products	3-(Trifluoromethyl)benzylamine

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