| ISOBUTYLMAGNESIUM BROMIDE Basic information |
| Product Name: | ISOBUTYLMAGNESIUM BROMIDE |
| Synonyms: | ISOBUTYLMAGNESIUM BROMIDE;Isobutylmagnesium bromide solution;ISOBUTYLMAGNESIUM BROMIDE, 2.0M SOLUTION IN DIETHYL ETHER;Isobutylmagnesium Bromide 1.0 M In Tetrahydrofuran;Isobutylmagnesium Bromide (17% in Tetrahydrofuran, ca. 1mol/L);Isobutylmagnesium bromide solution 2.0 in diethyl ether;Isobutylmagnesium bromide, 2M solution in diethyl ether, AcroSeal;2-Methylpropylmagnesium bromide |
| CAS: | 926-62-5 |
| MF: | C4H9BrMg |
| MW: | 161.32 |
| EINECS: | |
| Product Categories: | Grignard Reagent;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents |
| Mol File: | 926-62-5.mol |
| ISOBUTYLMAGNESIUM BROMIDE Chemical Properties |
| Melting point | 51-53℃ |
| Boiling point | 122-123℃ (0.2 Torr) |
| density | 0.941 g/mL at 25 °C |
| Fp | <−30 °F |
| InChIKey | CMWBEISSZHZIMU-UHFFFAOYSA-M |
| CAS DataBase Reference | 926-62-5 |
| Safety Information |
| Hazard Codes | F+,C,Xn |
| Risk Statements | 12-14/15-19-22-34-67-66 |
| Safety Statements | 16-26-36/37/39-45 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| HazardClass | 4.2 |
| PackingGroup | I |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ISOBUTYLMAGNESIUM BROMIDE Usage And Synthesis |
| Chemical Properties | Yellow to dark brown liquid |
| Uses | Isobutylmagnesium bromide (iBuMgBr) is a general Grignard reagent used in the total synthesis of (+)-rishirilide B, glucolipsin A, and (+)-juvabione. It can also be used as a reagent in the synthesis of pyrrolidine-based influenza neuraminidase (NA) inhibitors. |
| ISOBUTYLMAGNESIUM BROMIDE Preparation Products And Raw materials |
| Raw materials | 1-Bromo-2-methylpropane |
| Preparation Products | Isobutaneboronic acid-->2,6-DIMETHYL-3-HEPTENE-->Isopentyl ether-->12-methyl-1-tridecanol-->1-ACENAPHTHENOL |
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