Other grades of this product :
| 1,3-CYCLOHEPTADIENE Basic information |
| 1,3-CYCLOHEPTADIENE Chemical Properties |
| Melting point | -110.4°C | | Boiling point | 120-121 °C (lit.) | | density | 0.868 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.498(lit.) | | Fp | 52 °F | | storage temp. | 2-8°C | | Water Solubility | 619.2mg/L(temperature not stated) | | BRN | 1847604 |
| Hazard Codes | F,Xn | | Risk Statements | 11-65 | | Safety Statements | 16-23-24/25-62 | | RIDADR | UN 3295 3/PG 2 | | WGK Germany | 3 | | F | 23 | | HazardClass | 3.1 | | PackingGroup | II |
| 1,3-CYCLOHEPTADIENE Usage And Synthesis |
| Uses | 1,3-Cycloheptadiene was used in the preparation of enantiopure epoxy cycloheptenyl sulfones. | | General Description | 1,3-Cycloheptadiene is a 1,3-cycloalkadiene. Isomerization of highly strained (E,E)-1,3-cycloheptadiene was investigated through double bond rotation, and electrocyclic ring closure. [1,5] Sigmatropic hydrogen shifts in 1,3-cyclohepatdiene were studied by density functional calculations. | | Purification Methods | Purify the diene by dissolving it in Et2O, washing with 5% HCl, H2O, drying (MgSO4), evaporating, and the residue is distilled under dry N2 through a semi-micro column (some foaming occurs) [Cope et al. J Am Chem Soc 79 6287 1957, UV: Pesch & Friess J Am Chem Soc 72 5756 1950]. [Beilstein 5 IV 390.] |
| 1,3-CYCLOHEPTADIENE Preparation Products And Raw materials |
|
日本语
한국어
Français
Deutsch
España
Türkiye