Product

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE

CAS No.：40648-92-8

Other grades of this product :

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Basic information

Product Name:	(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE
Synonyms:	(-)-BIS[(S)-ALPHA-METHYLBENZYL]AMINE HYDROCHLORIDE;(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE;(S,S)-(-)-BIS(ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE;(S,S)-(-)-BIS(1-PHENYLETHYL)AMINE HYDROCHLORIDE;[S-(R,R)]-(-)-BIS(-ALPHA-METHYLBENZYL)AMINE HYDROCHLORIDE;(S,S)-(-)-Bis(α-methylbenzyl)amineHydrochloride;(-)-Bis[(S)-1-phenylethyl]amineHCl;(-)-bis[(s)-α-methylbenzyl]amine hydrochloride
CAS:	40648-92-8
MF:	C16H20ClN
MW:	261.79
EINECS:
Product Categories:	chiral;Asymmetric Synthesis;Synthetic Organic Chemistry
Mol File:	40648-92-8.mol

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Chemical Properties

Melting point	261-263 °C(lit.)
refractive index	-73 ° (C=3, EtOH)
storage temp.	Inert atmosphere,Room Temperature
form	powder to crystal
color	White to Almost white
optical activity	[α]20/D 73±2°, c = 3% in ethanol
BRN	4723969

Safety Information

Hazard Codes	Xi,Xn
Risk Statements	36/37/38-22
Safety Statements	26-36-36/37/39
WGK Germany	3
F	3

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Usage And Synthesis

Chemical Properties

white to light yellow crystal powde

Uses

(?)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used:

To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylphosphine.
As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides.
As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenediolato) phosphate(V) anion using ³¹P NMR.

(-)-BIS[(S)-1-PHENYLETHYL]AMINE HYDROCHLORIDE Preparation Products And Raw materials

Raw materials

Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->Palladium-->Sodium borohydride-->Di-tert-butyl dicarbonate-->Acetophenone-->L-1-Phenylethylamine

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