(S)-(+)-KETOPINIC ACID

CAS No.：40724-67-2

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(S)-(+)-KETOPINIC ACID Basic information

Uses

Product Name:	(S)-(+)-KETOPINIC ACID
Synonyms:	(1S)-(+)-KETOPINIC ACID;(1S)-(+)-KETOPINIC ACID 97+%;(1s)-7,7-dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic acid;(S)-7,7-DIMETHYL-2-OXO-BICYCLO[2.2.1]HEPTANE-1-CARBOXYLIC ACID;(S)-(+)-KETOPINIC ACID;rac-(1S,4R)-2-Oxobornane-10-oic acid;(1S,4R)-2-Oxobornane-10-oic acid;(1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]-1-carboxylic acid
CAS:	40724-67-2
MF:	C10H14O3
MW:	182.22
EINECS:
Product Categories:	Asymmetric Synthesis;Bicyclic Monoterpenes;Chiral Reagents;Biochemistry;Synthetic Organic Chemistry;Terpenes
Mol File:	40724-67-2.mol

(S)-(+)-KETOPINIC ACID Chemical Properties

Melting point	237-239 °C(lit.)
alpha	58 º (C=1 IN CHLOROFORM)
Boiling point	313.3±25.0 °C(Predicted)
density	1.238±0.06 g/cm3(Predicted)
refractive index	25.5 ° (C=0.65, MeOH)
storage temp.	Sealed in dry,Room Temperature
pka	3.67±0.40(Predicted)
form	powder to crystal
color	White to Almost white
optical activity	[α]23/D +58°, c = 1 in chloroform
BRN	4180005
CAS DataBase Reference	40724-67-2(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HS Code	2918300090

MSDS Information

(S)-(+)-KETOPINIC ACID Usage And Synthesis

Uses	7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.
Uses	(1S)-(+)-Ketopinic acid may be used to prepare: Chiral phosphine-oxazoline ligands, which can used in asymmetric palladium-catalyzed Heck reaction of aryl or alkenyl triflates with cyclic alkenes. A chiral imino-phosphine ligand, which can be used in palladium-catalyzed asymmetric Diels–Alder reactions to prepare six-membered carbocycles. A chiral iminopyridine ligand, which can be used in copper-catalyzed Henry (nitro aldol) reaction between nitromethane and o-anisol to form the corresponding β-hydroxynitroalkane.
Uses	7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-carboxylic Acid is a useful reactant for the preparation of alkenyl nitrile electrophiles for the possible use of covalent protein labeling.
General Description	(1S)-(+)-Ketopinic acid is a chiral ketone.

(S)-(+)-KETOPINIC ACID Preparation Products And Raw materials

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