DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)

DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
  • CAS No.:12148-71-9
Other grades of this product :
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Basic information
Description
Product Name:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I)
Synonyms:DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I);Di-mu-methoxobis(1,5-cyclooctadiene)diiridium(I),min.98%;[Ir(OMe)(1,5-cod)]2;BIS(1,5-CYCLOOCTADIENE) DI-MU-METHOXYDII;[Ir(OMe)(1;5-cod)]2;(1,5-Cyclooctadiene)(methoxy)iridium dimer;Bis(1,5-cyclooctadiene)dimethoxydiiridium
CAS:12148-71-9
MF:C18H22Ir2O2
MW:654.81
EINECS:628-411-6
Product Categories:organometallic complex;Metal Catalysts;Ir
Mol File:12148-71-9.mol
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Chemical Properties
Melting point 154-179 °C (D)
storage temp. -20°C
form Powder
color yellow
Sensitive Light, Air & Moisture Sensitive
InChIKeyWLPGZWOTJGJODI-SXGOCSEPSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26
WGK Germany 3
TSCA No
HS Code 2843909000
MSDS Information
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Usage And Synthesis
DescriptionDI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I), also known as methoxy(cyclooctadiene)iridium(I) dimer, is used as a catalyst in the preparation of heteroaryl fused indole ring systems as inhibition of HCV NS5B polymerase and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration. It is a powerful C-H activation catalyst to prepare phenols from arenes. It is also the catalyst of ortho-silylation of aryl ketone, benzaldehyde, and benzyl alcohol derivatives via C-H activation.
Chemical Propertiesyellow solid
UsesMethoxy(cyclooctadiene)iridium(I) dimer is used as a catalyst in the preparation of heteroaryl fused indole ring systems and borylation and Suzuki-miyaura coupling. Further, it is used in tetraborylation reactions, ortho-silylation of aryl ketone, benzaldehyde and benzyl alcohol derivatives through C-H activation. The most useful application is highly regio and enantio selection asymmetric hydroboration.
DI-MU-METHOXOBIS(1,5-CYCLOOCTADIENE)DIIRIDIUM(I) Preparation Products And Raw materials

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