Methyl 2-methyl-3-nitrobenzoate

Methyl 2-methyl-3-nitrobenzoate
  • CAS No.:59382-59-1
Other grades of this product :
Methyl 2-methyl-3-nitrobenzoate Basic information
Product Name:Methyl 2-methyl-3-nitrobenzoate
Synonyms:3-NITRO-O-TOLUIC ACID METHYL ESTER;3-NITRO-0-TOLUIC ACID METHYL ESTER;3-Nitro-o-toluic acid methyl ester (COOCH3=1);Methyl 3-nitro-2-methylbenzoate;Benzoic acid, 2-methyl-3-nitro-, methyl ester;Methyl 2-methyl-3-nitrobenzoate, 98+%;METHYL 3-NITRO-O-TOLUATE;METHYL 2-METHYL-3-NITROBENZENECARBOXYLATE
CAS:59382-59-1
MF:C9H9NO4
MW:195.17
EINECS:
Product Categories:API intermediates;Aromatic Esters;FINE Chemical & INTERMEDIATES;blocks;Carboxes;NitroCompounds
Mol File:59382-59-1.mol
Methyl 2-methyl-3-nitrobenzoate Chemical Properties
Melting point 62-65 °C (lit.)
Boiling point 286.6±20.0 °C(Predicted)
density 1?+-.0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
solubility Soluble in methanol.
form Solid
color Pale Beige
BRN 1964020
CAS DataBase Reference59382-59-1(CAS DataBase Reference)
Safety Information
Safety Statements 24/25
WGK Germany 3
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
Methyl 2-methyl-3-nitrobenzoate Usage And Synthesis
Chemical PropertiesWhite crystalline powder
UsesMethyl 2-methyl-3-nitrobenzoate may be used in the synthesis of methyl indole-4-carboxylate, 5-aminoisoquinolin-1(2H)-one, 5-nitroisocoumarin and [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone. It may also be used in the preparation of substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO; and 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis.
UsesMethyl 2-methyl-3-nitrobenzoate may be used in the synthesis of:
  • methyl indole-4-carboxylate
  • 5-aminoisoquinolin-1(2H)-one
  • 5-nitroisocoumarin
  • substituted nitrostyrene benzoic acids, via reaction with aromatic aldehydes in the presence of DBU in DMSO
  • 4-(hydroxymethyl)-1-tosylindole, via Batcho-Leimgruber modification of the Reissert indole synthesis
  • [2-(4-fluorophenyl)-1H-indol-4-yl]-1-pyrrolidinylmethanone

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