| Tris(triphenylphosphine)ruthenium(II) chloride Basic information |
| Product Name: | Tris(triphenylphosphine)ruthenium(II) chloride |
| Synonyms: | RUTHENIUM(II)-TRIS(TRIPHENYLPHOSPHINE) DICHLORIDE;RUTHENIUM DICHLOROTRIS(TRIPHENYLPHOSPHINE);TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(2) DICHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) CHLORIDE;TRIS(TRIPHENYLPHOSPHINE)RUTHENIUM(II) DICHLORIDE;Tris(triphenylphosphine)ruthenium(II) chloride≥ 99.5% (Assay);Tris(triphenylphosphine)ruthenium(II) chloride (10.5% Ru) for synthesis;DICHLOROTRIS(TRIPHENYLPHOSPHINE)RUTHENATE (II) |
| CAS: | 15529-49-4 |
| MF: | C54H45Cl2P3Ru |
| MW: | 958.83 |
| EINECS: | 239-569-7 |
| Product Categories: | Ru;metal-phosphine complexes;Catalysts for Organic Synthesis;Classes of Metal Compounds;Environmentally-friendly Oxidation;Homogeneous Catalysts;Metal Compounds;Metal Complexes;Ru (Ruthenium) Compounds;Synthetic Organic Chemistry;Transition Metal Complexes (Environmentally-friendly Oxidation);Transition Metal Compounds;chemical reaction,pharm,electronic,materials |
| Mol File: | 15529-49-4.mol |
| Tris(triphenylphosphine)ruthenium(II) chloride Chemical Properties |
| Melting point | 159 °C |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Very slightly soluble (with dissociation) in acetone, alcohol, chloroform, ethyl acetate, and toluene |
| form | Solution |
| color | Clear |
| Water Solubility | insoluble |
| Sensitive | Air & Moisture Sensitive |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| BRN | 4935939 |
| InChIKey | QUVLSIIMVTXAPD-UHFFFAOYSA-M |
| CAS DataBase Reference | 15529-49-4(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 20/21/22-20/21 |
| Safety Statements | 36/37-22 |
| RIDADR | 2811 |
| WGK Germany | 3 |
| TSCA | No |
| HS Code | 28439000 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| ALFA | English |
| Tris(triphenylphosphine)ruthenium(II) chloride Usage And Synthesis |
| Chemical Properties | black crystals |
| Uses | suzuki reaction |
| Uses | Dichlorotris(triphenylphosphine)ruthenium(II) serves as a precatalyst for the hydrogenation of alkenes, nitro compounds, ketones, carboxylic acids, synthesis of furans from allenyl sulfides and C-H Activation Catalyst in a Ruthenium/Lewis Acid System |
| Tris(triphenylphosphine)ruthenium(II) chloride Preparation Products And Raw materials |
| Raw materials | Ethanol-->Tetrahydrofuran-->Dichloromethane-->Isopropyl alcohol-->Hydrazinium hydroxide solution-->Triphenylphosphine-->Lithium-->Ruthenium(III) chloride hydrate(1:x) |
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