1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
  • CAS No.:17082-61-0
Other grades of this product :
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Basic information
Product Name:1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE
Synonyms:1,2-Bis(triMethylsiloxy)cyclobutene >=95%;4-methoxy-2-vinylbenzenamine ≥2-Chloro-1,3-thiazole ≥2,6-diethylpyridine ≥3-Bromo-5-ethyl-2-methylpyridine ≥(4-Methyl-1,3-thiazol-2-yl)methanol ≥Methyl 3-(3-bromophenyl)-3-oxopropanoate ≥tert-Butyl 3-(bromomethyl)pyrrolidine-1-carboxylate &ge
CAS:17082-61-0
MF:C10H22O2Si2
MW:230.45
EINECS:
Product Categories:Cyclobutanes & Cyclobutenes;Monoalkoxysilanes;Si (Classes of Silicon Compounds);Silicon Compounds (for Synthesis);Simple 4-Membered Ring Compounds;Si-O Compounds;Synthetic Organic Chemistry;Enol Ethers;Organic Building Blocks;Oxygen Compounds
Mol File:17082-61-0.mol
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Chemical Properties
Boiling point 58-59 °C2 mm Hg(lit.)
density 0.897 g/mL at 25 °C(lit.)
refractive index n20/D 1.435(lit.)
Fp 142 °F
storage temp. Inert atmosphere,2-8°C
form clear liquid
color Colorless to Light yellow
Specific Gravity0.87
Hydrolytic Sensitivity7: reacts slowly with moisture/water
BRN 1367530
InChIKeyWOBRFSDEZREQAB-UHFFFAOYSA-N
CAS DataBase Reference17082-61-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
RIDADR 1993
WGK Germany 3
10-21
TSCA No
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Usage And Synthesis
Chemical Propertiesclear colorless liquid
Uses1,2-Bis(trimethylsilyloxy)cyclobutene is a useful chemical reactant used in the preparation and biological activity of serine and threonine β-lactones as inhibitors of hepatitis A virus 3C cysteine proteinase.
General DescriptionPhotocycloaddition of 2-cyclohexenones to 1,2-bis(trimethyl-siloxy)cyclobutene has been studied. It undergoes Aldol condensation reaction with carbonyl compounds. It reacts with Br2 to give cyclobutanedione.
1,2-BIS(TRIMETHYLSILYLOXY)CYCLOBUTENE Preparation Products And Raw materials
Preparation Products2-(benzyloxy)cyclobutan-1-one-->2-Methyl-1,3-cyclopentanedione

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