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| ALLYLDIPHENYLPHOSPHINE OXIDE Basic information |
| ALLYLDIPHENYLPHOSPHINE OXIDE Chemical Properties |
| Melting point | 110-114 °C(lit.) | | Boiling point | 200-202 °C(Press: 2 Torr) | | density | 1.0769 g/cm3 | | storage temp. | under inert gas (nitrogen or Argon) at 2-8°C | | form | solid |
| Hazard Codes | Xi | | Risk Statements | 36/37/38 | | Safety Statements | 26-36 | | WGK Germany | 3 |
| ALLYLDIPHENYLPHOSPHINE OXIDE Usage And Synthesis |
| Uses | Reactant for:- Preparaton of a-substituted alkylsilanes via regio- and chemoselective copper-catalyzed silylzincation and electrophilic substitution from terminal alkenes, and prepn. of α-substituted alcohols via Fleming-Tamao oxidation of alkylsilanes
- Olefin isomerization with Grubbs′ catalysts occluded in a hydrophobic matrix of polydimethylsiloxane (PDMS)
- C9-substituted trans-hydrindene via diastereotopic group-selective intramolecular Diels-Alder reaction
- Isomerization of allyl group-containing compounds to propenyl group-containing compounds in the presence of a Grubbs second-generation Ru catalyst
- Ruthenium-catalyzed olefin cross-metathesis of vinyl and allyl phosphine oxides to give alkenyl phosphine oxides and bis-phosphine oxides
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| ALLYLDIPHENYLPHOSPHINE OXIDE Preparation Products And Raw materials |
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