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| Borane-methyl sulfide complex Basic information |
| Product Name: | Borane-methyl sulfide complex | | Synonyms: | Borane diMethyl sulfide coMplex technical, >90% in diMethyl sulfide;Borane diMethyl sulfide coMplex, 1.0 M solution in Methylene chloride, SpcSeal;Borane diMethyl sulfide coMplex, 10.0 M solution in DMS, SpcSeal;Borane diMethyl sulfide coMplex, 2.0 M solution in THF, SpcSeal;Borane diMethyl sulfide coMplex, 2.0 M solution in toluene, SpcSeal;Borane dimethyl sulfide complex solution
1.0 M in methylene chloride;Borane diMethyl sulfide coMplex, 5.0 M solution in diethyl ether, SpcSeal;Trihydro[thiobis[methane]]boron | | CAS: | 13292-87-0 | | MF: | C2H10BS | | MW: | 76.97 | | EINECS: | 236-313-6 | | Product Categories: | borane;Synthetic Reagents;B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry;API intermediates | | Mol File: | 13292-87-0.mol |
| Borane-methyl sulfide complex Chemical Properties |
| Melting point | -40--37°C | | Boiling point | ~34 °C | | density | 1.287 g/mL at 25 °C | | refractive index | 1.4570 | | Fp | 65 °F | | storage temp. | 2-8°C | | solubility | Miscible with ethyl ether, tetrahydrofurane, dichloromethane, benzene, xylene, hexane, diglyme, dimethyl ether, ethyl acetate, toluene, methylene chloride and other aprotic solvents. | | form | Solution | | Specific Gravity | 0.801 | | color | Colorless to pale yellow | | Water Solubility | reacts | | Sensitive | Air & Moisture Sensitive | | BRN | 3663489 | | InChIKey | RMHDLBZYPISZOI-UHFFFAOYSA-N | | CAS DataBase Reference | 13292-87-0(CAS DataBase Reference) | | NIST Chemistry Reference | Borane-methyl sulfide complex(13292-87-0) | | EPA Substance Registry System | Boron, trihydro[thiobis[methane]]-, (T-4)- (13292-87-0) |
| Borane-methyl sulfide complex Usage And Synthesis |
| Chemical Properties | clear colorless to light yellow solution | | Uses | Borane-dimethyl sulfide complex is used for hydroborations and reductions. Used with a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones. CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols. Highly enantioselective reduction of ketones catalyzed by C3-symmetric tripodal hydroxyamides. | | Uses | Borane-dimethyl sulfide (BH3 Me2S) can be used as a reagent: - For the selective synthesis of 1,3,5-oxygenated compounds from dimethyl 3-oxoglutarate.
- For the conversion of ozonides to alcohols.
- In the CBS-catalyzed asymmetric reduction of ferrocenyl-1,3-diketones to 1,3-diols.
- For enantioselective reduction of ketones to chiral secondary alcohols in the presence of C3-symmetric tripodal hydroxyamide as a ligand.
- For the hydroboration reduction and other applications.
- With a dendrimeric supported L-pyrrolidinol in the asymmetric reduction of indanones and tetralones.
| | General Description | Borane dimethyl sulfide complex (BMS) acts as a highly efficient and selective reducing agent in the presence of catalytic sodium tetrahydroborate for α-hydroxy esters. Asymmetric borane reduction of a variety of prochiral ketones with BMS using spiroborate esters as catalyst has been reported. |
| Borane-methyl sulfide complex Preparation Products And Raw materials |
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