Product

(S)-1-Benzyl-3-pyrrolidinol

CAS No.：101385-90-4

Other grades of this product :

(S)-1-Benzyl-3-pyrrolidinol Basic information

Product Name:	(S)-1-Benzyl-3-pyrrolidinol
Synonyms:	(s)-(-)-n-benzyl 3-hydroxypyrrolidine(S)-3-Hydroxy-1-benzyl-pyrrolidine1-(phenylmethyl)-3-pyrrolidinol;(S)-(-)-1-BENZYL-3-HYDROXYPYRROLIDINE , EE 99%;(S)-N-Benzyl-3-hydroxypyrrolidone;(S)-3-HYDROXY-1-BENZYL-PYRROLIDINE 98%;(S)-(-)-1-Benzyl-3-hydroxypyrrolidine, 99%, ee 99%;(3S)-1-Benzyl-3-hydroxypyrrolidine;(3S)-1-Benzyl-3-pyrrolidinol;(3S)-1-Benzylpyrrolidine-3β-ol
CAS:	101385-90-4
MF:	C11H15NO
MW:	177.24
EINECS:	600-202-4
Product Categories:	Pyrrole&Pyrrolidine&Pyrroline;Alcohols and Derivatives;Chiral Building Blocks;Simple Alcohols (Chiral);Synthetic Organic Chemistry;Heterocyclic Building Blocks;Benzenes;Chiral Building Blocks;Heterocyclic Building Blocks;Pyrrolidines
Mol File:	101385-90-4.mol

(S)-1-Benzyl-3-pyrrolidinol Chemical Properties

alpha	-3.7 º (c=5, MeOH)
Boiling point	115 °C0.8 mm Hg(lit.)
density	1.07 g/mL at 25 °C(lit.)
refractive index	n20/D 1.548(lit.)
Fp	>230 °F
storage temp.	2-8°C
form	Liquid
pka	14.82±0.20(Predicted)
color	Clear light yellow to pale brown
optical activity	[α]24/D 3.7°, c = 5 in methanol
BRN	4982831
InChIKey	YQMXOIAIYXXXEE-NSHDSACASA-N
CAS DataBase Reference	101385-90-4(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-37/39
WGK Germany	3
HS Code	29339900

MSDS Information

Provider	Language
SigmaAldrich	English
ALFA	English

(S)-1-Benzyl-3-pyrrolidinol Usage And Synthesis

Chemical Properties	Clear light yellow liquid
Uses	For synthesis of optically active products

(S)-1-Benzyl-3-pyrrolidinol Preparation Products And Raw materials

Raw materials

Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Methanol-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Lithium Aluminum Hydride-->Sodium borohydride-->Acetyl chloride-->Calcium chloride-->Benzylamine-->L-Malic acid-->2,5-Pyrrolidinedione,3-(acetyloxy)-1-(phenylmethyl)-, (3S)--->3-Pyrrolidinol, 1-[(2-aminophenyl)methyl]-, (3S)--->(S)-4-BROMO-1,2-EPOXYBUTANE-->(S)-1-BENZYL-4-HYDROXY-2-PYRROLIDINONE

Preparation Products

(3S)-(-)-3-(DIMETHYLAMINO)PYRROLIDINE-->(3R)-(+)-3-(DIMETHYLAMINO)PYRROLIDINE-->(S)-1-Boc-3-methanesulfonyloxy-pyrrolidine

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