2-Chloro-1,3-dimethylimidazolidinium chloride

CAS No.：37091-73-9

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2-Chloro-1,3-dimethylimidazolidinium chloride Basic information

Description Sources

Product Name:	2-Chloro-1,3-dimethylimidazolidinium chloride
Synonyms:	1,3-DIMETHYL-2-CHLOROIMIDAZOLINIUM CHLORIDE;2-CHLORO-1,3-DIMETHYLIMIDAZOLIDINIUM CHLORIDE;2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM CHLORIDE;Chlorodimethyllimidazoliniumchloride;2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM CHLOR;2-CHLORO-1,3-DIMETHYLIMIDAZOLIUM CHLORIDE;2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM CHLORIDE: (CA. 25% IN DICHLOROMETHANE);2-CHLORO-1,3-DIMETHYLIMIDAZOLINIUM CHLORIDE 98+%
CAS:	37091-73-9
MF:	C5H10Cl2N2
MW:	169.05
EINECS:	629-540-0
Product Categories:	Amines;Heterocycles;Biochemistry;Condensation & Active Esterification;Coupling Reactions (Peptide Synthesis);Peptide Synthesis;Synthetic Organic Chemistry;Phosphonium/Uronium/Formamidinium;Phosphonium/Uronium/FormamidiniumSynthetic Reagents;Coupling;Peptide Synthesis
Mol File:	37091-73-9.mol

2-Chloro-1,3-dimethylimidazolidinium chloride Chemical Properties

Melting point	133-140 °C (lit.)
storage temp.	Inert atmosphere,Store in freezer, under -20°C
solubility	Chloroform, Methanol, Water
form	Powder or Crystalline Powder
color	White to off-white
Merck	13,3424
Stability:	Hygroscopic
InChIKey	AEBBXVHGVADBHA-UHFFFAOYSA-M
CAS DataBase Reference	37091-73-9(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
RIDADR	1593
WGK Germany	3
F	3-10-21
HazardClass	6.1
PackingGroup	III
HS Code	29332900

MSDS Information

Provider	Language
SigmaAldrich	English

2-Chloro-1,3-dimethylimidazolidinium chloride Usage And Synthesis

Description	2-Chloro-1,3-dimethylimidazolidinium chloride has various applications including being used as activating agent in total synthesis of macroviracin A, cycloviracin B1 and cyclic silanes; used as reagent for synthesis of tagged glucose as an intermediate in the synthesis of branched oligosaccharides; used as fluorescent chemosensors; 1,2-Diamines as inhibitors of co-activator associated arginine methyltransferase¹; used as allosteric glucokinase activators; as reactant for synthesis of organic azides from primary amines and for aza-Henry reactions1. It can act as a powerful dehydrating agent, replacing DCC under nearly neutral conditions, and has application for the construction of heterocycles². Moreover, it can be used for one-pot synthesis of 2-aminobenzimidazoles³. It is also applicable to chlorination, oxidation, reduction, and rearrangement under nearly neutral conditions⁴.
Sources	https://www.sigmaaldrich.com/catalog/product/aldrich/529249?lang=en&region=US https://pubs.acs.org/doi/abs/10.1021/jo990210y www.sciencedirect.com/science/article/pii/S004040391001395X J. Org. Chem., 1999, 64 (16), pp 5832–5835
Chemical Properties	Brown Solid
Uses	Used in the one-pot synthesis of 2-aminobenzimidazoles.
Uses	Reagent for synthesis of: Tagged glucose as an intermediate in the synthesis of branched oligosaccharides Fluorescent chemosensors 1,2-Diamines as inhibitors of co-activator associated arginine methyltransferase 1 Allosteric glucokinase activatorsReactant for synthesis of: Organic azides from primary aminesReagent for aza-Henry reactions

2-Chloro-1,3-dimethylimidazolidinium chloride Preparation Products And Raw materials

Preparation Products

2,2-Difluoro-1,3-dimethylimidazolidine

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