BENZYLOXYACETALDEHYDE

BENZYLOXYACETALDEHYDE
  • CAS No.:60656-87-3
Other grades of this product :
BENZYLOXYACETALDEHYDE Basic information
Product Name:BENZYLOXYACETALDEHYDE
Synonyms:BENZYLOXYACETALDEHYDE;(phenylmethoxy)acetaldehyde;2-Benzyloxyacetaldehyde;Benzyloxyacetaldehyde, stabilized, 95%;Benzyloxyacetaldehyde CAS;2-(Benzyloxy)ethanal;2-(Phenylmethoxy)acetaldehyde;a-(Benzyloxy)acetaldehyde
CAS:60656-87-3
MF:C9H10O2
MW:150.17
EINECS:262-349-7
Product Categories:Aromatics Compounds;Aromatics;Aldehydes;C9;Carbonyl Compounds
Mol File:60656-87-3.mol
BENZYLOXYACETALDEHYDE Chemical Properties
Boiling point 118-120 °C/13 mmHg (lit.)
density 1.069 g/mL at 25 °C (lit.)
refractive index n20/D 1.518(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Store in freezer, under -20°C
solubility Chloroform, Ethyl Acetate
form Oil
color Clear Colourless
Specific Gravity1.069
Stability:Temperature, Moisture Sensitive
InChIKeyNFNOAHXEQXMCGT-UHFFFAOYSA-N
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29124990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
BENZYLOXYACETALDEHYDE Usage And Synthesis
Chemical PropertiesPale Yellow Oil
UsesAcceptor; engineering of 2-deoxyribose 5-phosphate aldolase variants for enzymic preparation of β-ketols
UsesBenzyloxyacetaldehyde may be used in the following syntheses:
  • (3S,5S)-methyl 6-benzyloxy-3,5-dihydroxyhexanoate
  • (S)-5-benzyloxy-4-hydroxypentan-2-one
  • myxothiazols
UsesAcceptor; engineering of 2-deoxyribose 5-phosphate aldolase variants for enzymic preparation of -ketols
General DescriptionBenzyloxyacetaldehyde is a non-natural aldehyde. It undergoes enantioselective Mukaiyama aldol reaction with silylketene acetal nucleophiles in the presence of C2-symmetric bis(oxazolinyl)pyridine Cu(II) complex (catalyst).

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