2,4-Dimethoxybenzoic acid

2,4-Dimethoxybenzoic acid
  • CAS No.:91-52-1
Other grades of this product :
2,4-Dimethoxybenzoic acid Basic information
Product Name:2,4-Dimethoxybenzoic acid
Synonyms:2,4-dimethoxy-benzoicaci;2,4-Dimethoxybenzoic acid, 98+%;2,4-Dimethoxybenzoic;Benzoic acid, 2,4-dimethoxy-;DIMETHOXYBENZOIC ACID,2,4-(RG);DIMETHOXYBENZOIC-2,4 ACID;DIMETHOXYBENZOIC ACID,2,4-;B-RESORCYLIC ACID DIMETHYL ETHER
CAS:91-52-1
MF:C9H10O4
MW:182.17
EINECS:202-074-1
Product Categories:Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts;Benzoic acid;Organic acids;C9;Carbonyl Compounds;Carboxylic Acids
Mol File:91-52-1.mol
2,4-Dimethoxybenzoic acid Chemical Properties
Melting point 107-109 °C (lit.)
Boiling point 275.56°C (rough estimate)
density 1.2481 (rough estimate)
refractive index 1.4500 (estimate)
storage temp. Sealed in dry,Room Temperature
form Powder
pka4.36±0.10(Predicted)
color White to off-white
Water Solubility slightly soluble
BRN 2210860
InChIKeyGPVDHNVGGIAOQT-UHFFFAOYSA-N
CAS DataBase Reference91-52-1(CAS DataBase Reference)
NIST Chemistry ReferenceBenzoic acid, 2,4-dimethoxy-(91-52-1)
EPA Substance Registry SystemBenzoic acid, 2,4-dimethoxy- (91-52-1)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39-36
WGK Germany 3
TSCA Yes
HS Code 29189090
MSDS Information
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2,4-Dimethoxybenzoic acid English
ACROS English
SigmaAldrich English
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2,4-Dimethoxybenzoic acid Usage And Synthesis
Chemical Propertieswhite to off-white powder
UsesYttrium and heavy lanthanide complexes is synthesised with 2, 4-dimethoxybenzoic acid and thermal and spectral features is studied. In the case of the electron-rich aromatic system 2,4-dimethoxybenzoic acid reduction of the intermediate HOBt ester is slow, and good.
Purification MethodsCrystallise the acid from water and dry it in a vacuum desiccator over H2SO4.. The S-benzylisothiuronium salt has m 158-159o (from CHCl3). [Beilstein 10 H 379, 10 I 177, 10 II 252, 10 III 1371, 10 IV 1422.] Aromatic acid impurities (to <0.05%) can be removed via the (±)--methylbenzylamine salt as described for 2,4-dichlorobenzoic acid [Ley & Yates Organic Process Research & Development 12 120 2008.]

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