3,4-METHYLENEDIOXYPHENYLBORONIC ACID

3,4-METHYLENEDIOXYPHENYLBORONIC ACID
  • CAS No.:94839-07-3
Other grades of this product :
3,4-METHYLENEDIOXYPHENYLBORONIC ACID Basic information
Product Name:3,4-METHYLENEDIOXYPHENYLBORONIC ACID
Synonyms:BENZO[D][1,3]DIOXOL-5-YLBORONIC ACID;RARECHEM AH PB 0145;TIMTEC-BB SBB003898;3,4-METHYLENEDIOXYBENZENEBORONIC ACID;3,4-METHYLENEDIOXYPHENYLBORONIC ACID;1,3-BENZODIOXOL-5-YLBORONIC ACID;1,3-Benzodioxole-5-boronic acid;3,4-Methylenedioxyphenylboroni
CAS:94839-07-3
MF:C7H7BO4
MW:165.94
EINECS:672-307-3
Product Categories:Aryl Boronic Acids;Boronic Acids and Derivatives;Boronic acids;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;blocks;BoronicAcids;Aryl;Boronic acid;Organoborons;Boronic Acids;Boronic Acids and Derivatives
Mol File:94839-07-3.mol
3,4-METHYLENEDIOXYPHENYLBORONIC ACID Chemical Properties
Melting point 224-229 °C(lit.)
Boiling point 347.3±52.0 °C(Predicted)
density 1.42±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
pka8.48±0.20(Predicted)
form Powder
color White to off-white
BRN 5523347
InChIKeyCMHPUBKZZPSUIQ-UHFFFAOYSA-N
CAS DataBase Reference94839-07-3(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 37/39-26
WGK Germany 3
HazardClass IRRITANT
HS Code 29163990
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
3,4-METHYLENEDIOXYPHENYLBORONIC ACID Usage And Synthesis
Chemical Properties3,4-METHYLENEDIOXYPHENYLBORONIC ACID is white powder
UsesReactant involved in:• ;Petasis reaction between glyoxylic acid, α-amino phosphonates, and organylboronic acids1• ;Mannich-type multicomponent assembly and 1,3-dipolar cycloaddition for synthesis of tetrahydroisoquinoline fused isoxazolidine scafford2• ;Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides3,4• ;Oxidative Heck reaction for synthesis of functionalized cinnamaldehyde derivatives5• ;Intramolecular Alder-ene and Pictet-Spengler reactions for synthesis of crinine6
Usessuzuki reaction
UsesReactant involved in:
  • Petasis reaction between glyoxylic acid, α-amino phosphonates, and organylboronic acids
  • Mannich-type multicomponent assembly and 1,3-dipolar cycloaddition for synthesis of tetrahydroisoquinoline fused isoxazolidine scafford
  • Suzuki-Miyaura cross-coupling of aryl and heteroaryl halides
  • Oxidative Heck reaction for synthesis of functionalized cinnamaldehyde derivatives
  • Intramolecular Alder-ene and Pictet-Spengler reactions for synthesis of crinine
3,4-METHYLENEDIOXYPHENYLBORONIC ACID Preparation Products And Raw materials
Raw materialsTetrahydrofuran-->Magnesium-->Trimethyl borate-->4-Bromo-1,2-(methylenedioxy)benzene
Preparation Products5-CHLORO-1,3-BENZODIOXOLE-->Piperonyl acetone

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