Formylhydrazine

Formylhydrazine
  • CAS No.:624-84-0
Other grades of this product :
Formylhydrazine Basic information
Product Name:Formylhydrazine
Synonyms:Formicacidhydrazide,98%;Formic acid hydrazide,95%;Formic hydrazine;ForMic acid hydrazide, 90% 25GR;ForMic hydrazid;FORMYLHYDRAZINE;FORMOHYDRAZIDE;FORMIC HYDRAZIDE
CAS:624-84-0
MF:CH4N2O
MW:60.06
EINECS:210-867-9
Product Categories:bc0001
Mol File:624-84-0.mol
Formylhydrazine Chemical Properties
Melting point 52-57 °C (lit.)
Boiling point 90°C/0.7mmHg(lit.)
density 1.094±0.06 g/cm3(Predicted)
refractive index 1.4840 (estimate)
Fp >230 °F
storage temp. Keep in dark place,Inert atmosphere,Store in freezer, under -20°C
solubility water: soluble2.5%, clear, colorless
pka13.65±0.20(Predicted)
form Shiny Crystalline Flakes
color White
Water Solubility Soluble
Sensitive Hygroscopic
BRN 635759
InChIKeyXZBIXDPGRMLSTC-UHFFFAOYSA-N
CAS DataBase Reference624-84-0(CAS DataBase Reference)
NIST Chemistry ReferenceFormic acid hydrazide(624-84-0)
EPA Substance Registry SystemHydrazinecarboxaldehyde (624-84-0)
Safety Information
Hazard Codes Xi,Xn
Risk Statements 36/37/38-20/21/22
Safety Statements 26-36-36/37/39
WGK Germany 3
RTECS LQ8615000
3-8-10
TSCA Yes
HS Code 29280000
MSDS Information
ProviderLanguage
Formic acid hydrazide English
SigmaAldrich English
ACROS English
ALFA English
Formylhydrazine Usage And Synthesis
Chemical PropertiesWHITE SHINY CRYSTALLINE FLAKES
UsesFormic acid hydrazide is used as a precursor in the preparation of 1,2,4-triazole derivatives. It is also used in the synthesis of 6-N-formylamino-12,13-dihydro-1,11-dihydroxy-13-(beta-D-glucopyranosyl)-5H-indolo[2,3-a]-pyrrolo[3,4-c]carbazole-5,7(6H)-dione, which is an anticancer agent.
Purification MethodsRecrystallise it from EtOH and dry it in vacuo. Store below 10o; it may disproportionate on storage to 1,2-diformyl hydrazine and hydrazine. It forms a blue [Cu(CH4N2O)]SO4 salt with CuSO4. [Beilstein 2 H 93, 2 III 127, 2 IV 85.]

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