Product

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride

CAS No.：14647-23-5

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1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Basic information

Product Name:	1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
Synonyms:	DICHLORO[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);DICHLORO[BIS(1,2-DIPHENYLPHOSPHINO)ETHANE]NICKEL(II);[Bis(diphenylphosphino)ethane]dichloronickel;1,2-BIS(DIPHENYLPHOSPHINE)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]DICHLORONICKEL(II);1,2-BIS(DIPHENYLPHOSPHINO)ETHANE NICKEL(II) CHLORIDE;[1,2-BIS(DIPHENYLPHOSPHINO)ETHANE]NICKEL(II) DICHLORIDE;1,2-Bis(diphenylphosphino)ethane nickel(II) chloride,98%
CAS:	14647-23-5
MF:	C26H24Cl2NiP2
MW:	528.02
EINECS:	629-489-4
Product Categories:	API intermediates;Catalysis and Inorganic Chemistry;Metal Compounds;Catalysts for Organic Synthesis;Chemical Synthesis;Ni;Classes of Metal Compounds;Homogeneous Catalysts;Metal Complexes;Ni (Nickel) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds;metal-phosphine complexes
Mol File:	14647-23-5.mol

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Chemical Properties

Melting point	263-265 °C(lit.)
storage temp.	Inert atmosphere,2-8°C
solubility	Chloroform, Methanol (Sparingly)
form	crystal
color	orange
Water Solubility	insoluble
Exposure limits	NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS DataBase Reference	14647-23-5(CAS DataBase Reference)

Safety Information

Hazard Codes	T,Xn
Risk Statements	45-20/21/22-36/37/38-42/43-40
Safety Statements	53-22-26-36-45-52
WGK Germany	3
TSCA	No
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English
ALFA	English

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Usage And Synthesis

Chemical Properties	Orange to red crystalline powder
Uses	suzuki reaction
Uses	Dichloro[bis(1,2-diphenylphosphino)ethane]nickel(II) is a reactant involved in Kumada catalyst-transfer polycondensation, oxidation of carboranyl phosphine ligands, synthesis of nickel-iron dithiolato hydrides, Ullmann reactions - homocoupling reactions, co-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centers, catalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

1,2-Bis(diphenylphosphino)ethane nickel(II) chloride Preparation Products And Raw materials

Raw materials

Ethanol-->Sodium hydroxide-->Hydrochloric acid-->Ethyl acetate-->Tetrahydrofuran-->Dichloromethane-->PETROLEUM ETHER-->Triphenylphosphine-->1,2-Dichloroethane-->Lithium-->1,2-Dibromoethane-->Nickel(II) chloride hexahydrate-->Diphenylphosphine

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