3-Dimethylaminopropylamine

3-Dimethylaminopropylamine
  • CAS No.:109-55-7
Other grades of this product :
3-Dimethylaminopropylamine Basic information
Product Name:3-Dimethylaminopropylamine
Synonyms:RARECHEM AL BW 0072;N,N-DIMETHYL PROPANE-1,3-DIAMINE;N,N-DIMETHYLTRIMETHYLENEDIAMINE;N,N-DIMETHYL-1,3-DIAMINOPROPANE;gamma-dimethylaminopropylamine;H2N(CH2)3N(CH3)2;N-(3-aminopropyl)dimethylamine;N,N-Dimethyl-1,3-propylenediamine
CAS:109-55-7
MF:C5H14N2
MW:102.18
EINECS:203-680-9
Product Categories:Building Blocks;Chemical Synthesis;amine series;Nitrogen Compounds;Organic Building Blocks;Polyamines
Mol File:109-55-7.mol
3-Dimethylaminopropylamine Chemical Properties
Melting point -60 °C
Boiling point 133 °C(lit.)
density 0.812 g/mL at 25 °C(lit.)
vapor density 3.6 (vs air)
vapor pressure 5 mm Hg ( 20 °C)
refractive index n20/D 1.435(lit.)
Fp 90 °F
storage temp. Store below +30°C.
form Liquid
pka10.13±0.10(Predicted)
color Clear
PH12.7 (100g/l, H2O, 20℃)
explosive limit2.3-12.35%(V)
Water Solubility SOLUBLE
FreezingPoint -70℃
Sensitive Air Sensitive
BRN 605293
InChIKeyIUNMPGNGSSIWFP-UHFFFAOYSA-N
LogP-0.352 at 25℃
CAS DataBase Reference109-55-7(CAS DataBase Reference)
NIST Chemistry Reference1,3-Propanediamine, N,N-dimethyl-(109-55-7)
EPA Substance Registry System3-(Dimethylamino)propylamine (109-55-7)
Safety Information
Hazard Codes C
Risk Statements 10-22-34-43-21/22
Safety Statements 26-36/37/39-45
RIDADR UN 2733 3/PG 3
WGK Germany 2
RTECS TX7525000
Autoignition Temperature215 °C
TSCA Yes
HazardClass 8
PackingGroup II
HS Code 29212900
Hazardous Substances Data109-55-7(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 1640 mg/kg
MSDS Information
ProviderLanguage
3-Aminopropyldimethylamine English
SigmaAldrich English
ACROS English
ALFA English
3-Dimethylaminopropylamine Usage And Synthesis
DescriptionDimethylaminopropylamine is an aliphatic amine present in amphoteric surfactants such as liquid soaps and shampoos. It is present as an impurity responsible for allergy from cocamidopropylbetaine. It is structurally similar to diethylaminopropylamine. It is also used as a curing agent for epoxy res ins and as an organic intermediate in chemical syntheses (ion exchangers, additives for flocculants, cosmetics and fuel additives, dyes and pesticides).
Chemical Propertiesclear liquid. soluble in water and organic solvents.
UsesN,N-Dimethyl-1,3-propylenediamine is a useful catalyst for Knoevenagel condensation. It is also a useful hardening agent for expoxy resin.
UsesUseful for cleavage of N-alkylphthalimide derivatives to give primary amines, as an alternative to methyl hydrazine. DMAPA is also used directly as a hardener in epoxy resins in the plastics industry, as a cross linking agent for cellulose fibers in the paper industry and as an anti-shriking agent for leather. It is used as an intermediate in the production of binding agents, ion-exchange materials, flocculating agents (water treatment), cosmetic agents, washing and cleaning agents (betaines), additive for petrol and other fuels, polyurethane fibers and lubricants, dyes, agrochemicals, agents used in the photographic and textile industries.
Uses3-(Dimethylamino)propylamine is an intermediate substance in the synthesis of alkylamidopropyldimethylamines/alkylamidobetaines; found as an impurity in cosmetic surfactants present in e.g. shampoos; hardener of epoxy resins; additive in fue!, dyes, pesticides and binding agents; in the production of ion-exchangers.
General DescriptionDimethylaminopropylamine is a colorless liquid. (NTP, 1992)
Air & Water ReactionsHighly flammable. Temperature sensitive and possibly sensitive to air. Water soluble.
Reactivity Profile3-Dimethylaminopropylamine neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Fire Hazard3-Dimethylaminopropylamine is flammable.
Safety ProfileModerately toxic by ingestion and skin contact. A skin and eye irritant. Very flammable when exposed to heat, flame, or oxidmers. Reaction with 1,2dichloroethane produces explosive acetylene gas. This and other amines igmte on contact with cellulose nitrate of hgh surface area. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of NO,. See also AMINES

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