2-Hydroxyethyl methacrylate

2-Hydroxyethyl methacrylate
  • CAS No.:868-77-9
Other grades of this product :
2-Hydroxyethyl methacrylate Basic information
Product Name:2-Hydroxyethyl methacrylate
Synonyms:1,2-ETHANEDIOL MONO(2-METHYLPROPENOATE);2-HYDROXYETHYL 2-METHYLPROPERIOATE;2-HYDROXYETHYL METHACRYLATE;1,2-Ethanediol, mono(2-methyl)-2-propenoate-;2-(Methacryloyloxy)ethanol;2-Hydroxyethyl 2-methylacrylate;2-Hydroxyethyl-2-methyl-2-propenoate;2-Methyl-2-propenoic acid, 2-hydroxyethyl ester
CAS:868-77-9
MF:C6H10O3
MW:130.14
EINECS:212-782-2
Product Categories:Industrial/Fine Chemicals;Aliphatics;Mutagenesis Research Chemicals;868-77-9
Mol File:868-77-9.mol
2-Hydroxyethyl methacrylate Chemical Properties
Melting point -12 °C
Boiling point 67 °C3.5 mm Hg(lit.)
density 1.073 g/mL at 25 °C(lit.)
vapor density 5 (vs air)
vapor pressure 0.01 mm Hg ( 25 °C)
refractive index n20/D 1.453(lit.)
Fp 207 °F
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
form Liquid
pka13.83±0.10(Predicted)
color Clear
OdorEster like
Water Solubility soluble
Sensitive Air Sensitive
BRN 1071583
Stability:Unstable - may polymerize in the absence of stabilizer. May be stabilized with, or contain small amounts of, diethylene glycol monomethacrylate, di(ethylene glycol)dimethacrylate, methacrylic acid. Incompatible with strong oxidizing agents, free radical initiators, peroxides, steel. Closed containers may explode if heated due to runaway polymer
InChIKeyWOBHKFSMXKNTIM-UHFFFAOYSA-N
LogP0.42 at 25℃
CAS DataBase Reference868-77-9(CAS DataBase Reference)
NIST Chemistry Reference2-Hydroxyethyl methacrylate(868-77-9)
EPA Substance Registry System2-Hydroxyethyl methacrylate (868-77-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/38-43-36/37/38
Safety Statements 26-36/37-28A-28
WGK Germany 1
RTECS OZ4725000
8
TSCA Yes
HS Code 29161490
Hazardous Substances Data868-77-9(Hazardous Substances Data)
ToxicityLD50 orally in Rabbit: 5050 mg/kg LD50 dermal Rabbit > 3000 mg/kg
MSDS Information
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2-Hydroxyethyl methacrylate English
SigmaAldrich English
ACROS English
ALFA English
2-Hydroxyethyl methacrylate Usage And Synthesis
Chemical Propertiescolourless liquid
Uses2-Hydroxyethyl methacrylate is used for preparation of hydrophilic polymers for biomedical devices.
Uses2-Hydroxyethyl methacrylate is the methacrylic monomer for use in UV inks, adhesives, lacquers, dental materials, artificial nails, etc.
Uses2-Hydroxyethyl methacrylate is used in UV-curable inks and coatings. It is also used in adhesives, artificial nails, dental materials and lacquers. In dentistry, it is one of the main volatile acrylates along with methyl methacrylate. Further, it is used as a monomer in the synthesis of polymers for dental prosthetics and for geotechnical grouting in construction work.
Definition2-Hydroxyethyl methacrylate is an enoate ester that is the monomethacryloyl derivative of ethylene glycol.
General Description2-Hydroxyethyl methacrylate (HEMA) is biocompatible in nature. Polymeric hydrogel scaffold can be produced by polymerizing HEMA in water.
Hazard30% grade (with xylene): Flammable, moderate fire risk.
Purification MethodsDissolve the ester in water and extract with n-heptane to remove ethylene glycol dimethacrylate (checked by gas-liquid chromatography and by NMR) and distil it twice under reduced pressure [Strop et al. J Phys Chem 80 694 1976]. [Beilstein 2 IV 1530.]

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