TERT-BUTYLMAGNESIUM CHLORIDE

CAS No.：677-22-5

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This product is a chemical product/pharmaceutical intermediate. It is not a drug, an active pharmaceutical ingredient (API), or a pharmaceutical-grade material. It has not been granted a drug approval number or a Chemical Drug Substance Approval Notice, has not passed drug-related review and approval, and is not manufactured, tested, or released in accordance with pharmaceutical GMP.
This product is intended solely for non-clinical research, process development, quality studies, further chemical processing, or chemical synthesis. It must not be used in drug-product manufacturing, clinical trials, clinical diagnosis, or administration to humans or animals, or be sold, used as an input, submitted for regulatory filing, or released as an API or pharmaceutical material.
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TERT-BUTYLMAGNESIUM CHLORIDE Basic information

Product Name:	TERT-BUTYLMAGNESIUM CHLORIDE
Synonyms:	tert-Butylmagnesium chloride, 1M in MeTHF;tert-Butylmagnesium chloride [1.0 M solution in THF];tert-Butylmagnesium chloride, 1,7M solution in diethyl ether, AcroSeal§3;tert-Butylmagnesium chloride, 1.7M solution in THF, AcroSeal;tert-Butylmagnesium chloride, 1.7M solution in diethyl ether, AcroSeal;tert-ButylMagnesiuM chloride ,1.0 M in tetrahydrofuran;tert-butylMagnesiuM;(1,1-Dimethylethyl)magnesium chloride
CAS:	677-22-5
MF:	C4H9ClMg
MW:	116.87
EINECS:	211-638-6
Product Categories:	Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Synthetic Organic Chemistry;Typical Metal Compounds;AlkylChemical Synthesis;Grignard Reagents;Organic Bases;Organometallic Reagents;Synthetic Reagents;Grignard Reagent;bc0001
Mol File:	677-22-5.mol

TERT-BUTYLMAGNESIUM CHLORIDE Chemical Properties

Melting point	-108℃ (Tetrahydrofuran)
density	0.931 g/mL at 25 °C
Fp	34 °F
storage temp.	2-8°C
form	Liquid
color	Clear brown to dark brown
Water Solubility	Miscible with alcohol and water.
Sensitive	Air & Moisture Sensitive
BRN	3535403
InChIKey	ZDRJSYVHDMFHSC-UHFFFAOYSA-M
CAS DataBase Reference	677-22-5(CAS DataBase Reference)

Safety Information

Hazard Codes	F+,C,F
Risk Statements	12-14/15-19-22-34-66-67-15-11-14-37-17-40
Safety Statements	9-16-26-29-33-36/37/39-43-45
RIDADR	UN 3399 4.3/PG 1
WGK Germany	1
F	1-3-10
HazardClass	4.3
PackingGroup	I
HS Code	29319090

MSDS Information

Provider	Language
SigmaAldrich	English
ACROS	English

TERT-BUTYLMAGNESIUM CHLORIDE Usage And Synthesis

Chemical Properties	clear faint grey to grey, grey-brown or light
Uses	tert-Butylmagnesium chloride is a Grignard reagent used in organic synthesis. It is also involved in copper-catalyzed cross-coupling reaction with primary-alkyl halides.

TERT-BUTYLMAGNESIUM CHLORIDE Preparation Products And Raw materials

Raw materials	Tetrahydrofuran-->Magnesium-->2-Chloro-2-methylpropane
Preparation Products	4-tert-Butylcyclohexanol-->2-Propanesulfinic acid,2-methyl--->2,2-DIMETHYL-1-BUTANOL-->N-tert-butylhydroxylamine-->2,2-DIMETHYL-3-HEXANOL-->2,2-DIMETHYL-3-HEXANONE-->DI-TERT-BUTYLPHENYLPHOSPHINE-->Pinacolone

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