Bis(dibenzylideneacetone)palladium

Bis(dibenzylideneacetone)palladium
  • CAS No.:32005-36-0
Other grades of this product :
Bis(dibenzylideneacetone)palladium Basic information
Reaction
Product Name:Bis(dibenzylideneacetone)palladium
Synonyms:BIS(DIBENZYLIDENEACETONE)PALLADIUM;BIS(DIBENZYLIDENEACETONE) PALLADIUM(0);PALLADIUM (0) BIS(DIBENZYLIDENEACETONE) SALT;PALLADIUM(0) BIS(DIBENZYLIDENEACETONE);PD(DBA)2;Bis(dibenzylideneacetone)palladium(0) Pd(dba)2Pd2(dba)3dba;BIS(DIBENZYLIDENEACETONE)PALLADIUM(O);Bis(dibenzylideneacetone)palladium(0) Pd(dba)2Pd2(dba)3ba
CAS:32005-36-0
MF:C34H20O2Pd
MW:566.95
EINECS:608-691-6
Product Categories:chemical reaction,pharm,electronic,materials;organometallic complex;Catalysts for Organic Synthesis;Classes of Metal Compounds;Catalysts-Ligands;Pd;Homogeneous Catalysts;Metal Complexes;Pd (Palladium) Compounds;Synthetic Organic Chemistry;Transition Metal Compounds
Mol File:32005-36-0.mol
Bis(dibenzylideneacetone)palladium Chemical Properties
Melting point 150°C
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
solubility Chloroform (Slightly)
form Fine Powder
color Red-brown to black
Water Solubility insoluble
Sensitive Air & Moisture Sensitive
InChIKeyWTAPZWXVSZMMDG-JZOPPWQGSA-N
CAS DataBase Reference32005-36-0(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 22-24/25-37/39-26
WGK Germany 3
TSCA No
HS Code 28439000
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
Bis(dibenzylideneacetone)palladium Usage And Synthesis
Reaction
  1. Palladium-catalyzed acylation of unsaturated halides by anions of enol ethers.
  2. Asymmmetric Allylation reactions.
  3. Intramolecular reactions with alkenes.
  4. Carbonylation reactions.
  5. Cross Coupling reactions.
Chemical Propertiespurple brown
Usessuzuki reaction
UsesHydrogenation, isomerization, carbonylation, oxidation, C-C bond formation.Bis(dibenzylideneacetone)palladium(0) is used as a reagent for the preparation of allylic substituted cyclopentadienes. It acts as a homogeneous catalyst as well as in the alkylation of allyl acetates by various nucleophiles. Further, it is used in Suzuki reaction.
UsesApplication Guide for Palladium Catalyzed Cross-Coupling Reactions
General DescriptionBis(dibenzylideneacetone)palladium(0) (Pd(dba)2) is an air stable Pd0 complex. It is a reagent for the synthesis of allylic substituted cyclopentadienes. It is a homogeneous catalyst. It catalyzes the alkylation of allyl acetates by various nucleophiles under mild conditions.
Bis(dibenzylideneacetone)palladium Preparation Products And Raw materials
Raw materialsMethanol-->Toluene-->Acetone-->Acetonitrile-->Sodium acetate-->Benzaldehyde-->Palladium chloride-->1,3-Dichloropropane
Preparation Productstrans-Bis(triphenylphosphine)palladium dichloride-->Bis[Tris(2-methylphenyl)phosphine]palladium

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