| Vinylmagnesium chloride Basic information |
| Product Name: | Vinylmagnesium chloride |
| Synonyms: | VINYLMAGNESIUM CHLORIDE;chlorovinylmagnesium;Vinylmagnesium;VINYLMAGNESIUM CHLORIDE, 1.6M SOLUTION IN TETRAHYDROFURAN;VINYLMAGNESIUM CHLORIDE SOLUTION, ~1.7 M IN TETRAHYDROFURAN;Vinylmagnesium chloride, 15 wt% solution in tetrahydrofuran;VINYLMAGNESIUMCHLORIDE,15%(W/W)SOLUTIONINTETRAHYDROFURAN;Chlorvinylmagnesium |
| CAS: | 3536-96-7 |
| MF: | C2H3ClMg |
| MW: | 86.8 |
| EINECS: | 222-575-9 |
| Product Categories: | Grignard Reagent;Alkenyl;Grignard Reagents;Organometallic Reagents |
| Mol File: | 3536-96-7.mol |
| Vinylmagnesium chloride Chemical Properties |
| Boiling point | 66 °C |
| density | 0.980 g/mL at 20 °C |
| Fp | −1 °F |
| storage temp. | 0-6°C |
| form | Crystalline Powder |
| color | White to beige |
| Water Solubility | vigorous reaction |
| BRN | 3535268 |
| InChIKey | NAFZXKWEUWVSAW-UHFFFAOYSA-M |
| CAS DataBase Reference | 3536-96-7(CAS DataBase Reference) |
| EPA Substance Registry System | Magnesium, chloroethenyl- (3536-96-7) |
| Safety Information |
| Hazard Codes | F,C |
| Risk Statements | 11-14/15-19-22-34-40-37 |
| Safety Statements | 16-26-36/37/39-43-45-7/8-43B-30 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| F | 1-3-10 |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| SigmaAldrich | English |
| ACROS | English |
| Vinylmagnesium chloride Usage And Synthesis |
| Chemical Properties | dark brown solution |
| Uses | Grignard reagent. |
| Uses | Vinylmagnesium chloride (Grignard reagent) can be prepared from vinyl chloride and then used to make a variety of useful end products or intermediates by adding a vinyl anion to organic functional groups. For instance, the vinylmagnesium compounds can be coupled with cuprous chloride, CuCl, at ?60 °C (?76 °F) to give 1,3-butadiene, while vinyl ketones and alcohols can be prepared by the addition of vinylmagnesium chloride to organic acids. |
| Uses | Used with iron pentadienoate complexes in a synthesis of divinyl cyclopropanes. |
| Vinylmagnesium chloride Preparation Products And Raw materials |
| Preparation Products | HEXAVINYLDISILOXANE-->(R)-(-)-PENTEN-2-OL-->1-PHENYL-1-CYCLOPROPANOL-->Trivinylboroxin-->Cinnamyl chloride-->3-Phenylpropene-3-ol |
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