ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98

CAS No.：478980-03-9

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ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Basic information

Reaction

Product Name:	ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98
Synonyms:	[1,3-bis(2,6-diisopropylphenyl)-2H-imidazol-2-yl]-chloro-palladium;Allylchloro[1,3-bis(2,6-di-i-propylphenyl);imidazol-2-ylidene]palladium(II);ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98;PALLADIUM(II);ALLYLCHLORO[1,3-BIS-(DIISOPROPYLPHENYL)-IMIDAZOLE-2-YLIDENE]PALLADIUM(II);Allylchloro[1,3-bis(2,6-di-i-propylphenyl)imidazol-2-ylidene]palladium;Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) 98%
CAS:	478980-03-9
MF:	C30H41ClN2Pd
MW:	571.53
EINECS:
Product Categories:	Pd;alkylidene complex
Mol File:	478980-03-9.mol

ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Chemical Properties

Melting point	190°C (dec.)
storage temp.	under inert gas (nitrogen or Argon) at 2–8 °C
form	Powder
color	white

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36/37/39-36/37
WGK Germany	3
HS Code	28439000

MSDS Information

ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Usage And Synthesis

Reaction	Catalyst for the cross-coupling of aryl chlorides with boronic acids. Catalyst for the diamination of conjugated dienes and trienes. Catalyst for the dehalogenation of aryl chlorides. Catalyst for anaerobic alcohol oxidation. Catalyst for anaerobic ketone oxidation and domino oxidation/α-arylation.
Chemical Properties	Yellow crystal
Uses	Catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.
General Description	Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II) is an air-stable, well-defined palladium N-heterocyclic carbene complex, which can efficiently catalyze α-arylation of ketones.

ALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II), 98 Preparation Products And Raw materials

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