1-Chloromethyl naphthalene
1-Chloromethyl naphthalene
  • CAS No.:86-52-2
Other grades of this product :
1-Chloromethyl naphthalene Basic information
Product Name:1-Chloromethyl naphthalene
Synonyms:1-(chloromethyl)-naphthalen;1-(Chloromethyl)naphthene;AKOS BBS-00004040;1-chloromethyl-naphthalen;1-Menaphthyl chloride;1-menaphthylchloride;1-(CHLOROMETHYL)NAPHTHALENE;1-CHLOROMETHYLNAPHTHYL
CAS:86-52-2
MF:C11H9Cl
MW:176.64
EINECS:201-678-2
Product Categories:API Intermediate;Naphthalene series;Aryl;Building Blocks;C9 to C12;Chemical Synthesis;Naphthalene derivatives;API intermediates;Halogenated Hydrocarbons;Organic Building Blocks;bc0001
Mol File:86-52-2.mol
1-Chloromethyl naphthalene Chemical Properties
Melting point 32 °C(lit.)
Boiling point 291 °C
density 1.18 g/mL at 25 °C(lit.)
refractive index n20/D 1.635(lit.)
Fp >230 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
form Liquid After Melting
Specific Gravity1.18
color deep brown
Water Solubility Insoluble in water.
Sensitive Moisture Sensitive
BRN 636885
InChIKeyXMWGTKZEDLCVIG-UHFFFAOYSA-N
LogP3.97 at 20℃
CAS DataBase Reference86-52-2(CAS DataBase Reference)
NIST Chemistry ReferenceNaphthalene, 1-(chloromethyl)-(86-52-2)
EPA Substance Registry SystemNaphthalene, 1-(chloromethyl)- (86-52-2)
Safety Information
Hazard Codes C,Xn
Risk Statements 21/22-34-36/37/38-36-20/21/22
Safety Statements 26-36/37/39-45-60-20-27
RIDADR UN 3261 8/PG 2
WGK Germany 3
RTECS QJ2800000
TSCA Yes
HazardClass 8
PackingGroup III
HS Code 29036990
MSDS Information
ProviderLanguage
1-Chloromethyl naphthalene English
SigmaAldrich English
ACROS English
ALFA English
1-Chloromethyl naphthalene Usage And Synthesis
Chemical PropertiesSolid
Uses1-(Chloromethyl)naphthalene is a key material for synthesis dye pigment and as fluorescent brightening agent. It is employed in synthetic resin and medicine. Palladium-catalyzed nucleophilic dearomatization of chloromethyl naphthalene derivatives produce ortho- or para-substituted carbocycles in satisfactory to excellent yields.
General DescriptionKinetics and dissociation mechanism of 1-(chloromethyl)naphthalene following 266nm photoexcitation has been studied. Intermolecular nucleophilic dearomatization of 1-chloromethyl naphthalene with various activated methylene compounds has been investigated.

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