4-Bromo-3-methylphenol

4-Bromo-3-methylphenol
  • CAS No.:14472-14-1
Other grades of this product :
4-Bromo-3-methylphenol Basic information
Product Name:4-Bromo-3-methylphenol
Synonyms:4-BROMO-3-METHYLPHENOL;4-BROMO-M-CRESOL;AKOS BBS-00008110;AURORA 4271;4-BROMO-3-METHYLPHENOLBRO7H7C;Phenol, 4-bromo-3-methyl-;4-Bromo-3-methylphenol,4-Bromo-m-cresol;4-BroMo-3-Methylphenol 98%
CAS:14472-14-1
MF:C7H7BrO
MW:187.03
EINECS:238-464-3
Product Categories:Phenyls & Phenyl-Het;Aromatic Phenols;Benzene series;Phenyls & Phenyl-Het;Phenol&Thiophenol&Mercaptan
Mol File:14472-14-1.mol
4-Bromo-3-methylphenol Chemical Properties
Melting point 59-61 °C (lit.)
Boiling point 142-145 °C/23 mmHg (lit.)
density 1.3839 (rough estimate)
refractive index 1.5772 (estimate)
Fp 142-145°C/23mm
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Methanol
form Crystalline Powder or Chunks
pka9.51±0.18(Predicted)
color White to off-white
BRN 1859122
CAS DataBase Reference14472-14-1(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36-37/39
WGK Germany 3
HazardClass IRRITANT
PackingGroup III
HS Code 29081990
MSDS Information
ProviderLanguage
4-Bromo-m-cresol English
ACROS English
SigmaAldrich English
ALFA English
4-Bromo-3-methylphenol Usage And Synthesis
Chemical Propertieswhite to off-white crystalline powder or chunks
Uses4-Bromo-3-methylphenol may be used in the synthesis of bromo[2-methyl-4-[2-(t-butyldimethylsilyloxy)ethyloxy]phenyl]bis(triphenylphopshine)nickel(II) (protected alcohol-functionalized initiator) and bromo-[2-methyl-4-[6-(t-butyldimethylsilyloxy)hexyloxy]phenyl] bis(triphenylphosphine) nickel.
General Description4-Bromo-3-methylphenol is a brominated phenol. It participates in the total synthesis of 3-methylcalix[4]arene.

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