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| Silver benzoate Basic information |
| Silver benzoate Chemical Properties |
| Melting point | >188°C (dec.) | | storage temp. | Keep in dark place,Inert atmosphere,Room temperature | | solubility | cold water: soluble385 part(lit.) | | form | Powder | | color | White to cream or gray | | Water Solubility | Insoluble in water. | | Sensitive | Light Sensitive | | InChIKey | CLDWGXZGFUNWKB-UHFFFAOYSA-M | | CAS DataBase Reference | 532-31-0(CAS DataBase Reference) | | EPA Substance Registry System | Benzoic acid, silver(1+) salt (532-31-0) |
| Safety Statements | 24/25 | | WGK Germany | 3 | | TSCA | Yes | | HS Code | 28432900 |
| Silver benzoate Usage And Synthesis |
| Chemical Properties | Off-White Crystalline Powder | | Uses | Silver benzoate is an aromatic salt that is used as a catalyst to prepare β-amino acids (such as N-Acetyl-β-alanine) from α-amino acids (such as D-Alanine). Silver benzoate is also used as a catalyst in Wolff rearrangement reactions. | | Application | Silver benzoate was used in the synthesis of triphenyltinbenzoate. It is an efficient catalytic system for the reaction of carbon dioxide with various ketones. | | Reactions | Silver benzoate reacts with bromine in CCl4 refluxing to form C6H5Br This reaction is called Hunsdiecker reaction. | | General Description | Silver benzoate along with 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene (MTBD) is an efficient catalytic system for the reaction of carbon dioxide with various ketones. | | Synthesis | Silver benzoate can be obtained by reacting silver nitrate and sodium benzoate: AgNO3 + PhCOONa → PhCOOAg↓ + NaNO3Reaction: Mix an equimolar amount of silver nitrate solution with sodium benzoate solution to precipitate silver benzoate. Washed with water and dried in a vacuum desiccator. |
| Silver benzoate Preparation Products And Raw materials |
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