(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

CAS No.：135139-00-3

Other grades of this product :

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Basic information

Reaction

Product Name:	(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
Synonyms:	1,1'-[(1S)-[1,1'-Binaphthalene]-2,2'-diyl]bis[1,1-bis(3,5-dimethylphenyl)-phosphine;2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;(S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , ((S)-Xylyl;(S)-(-)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl;(S)-3,5-Xyl-BINAP;(S)-DM-BINAP;Xylbinap
CAS:	135139-00-3
MF:	C52H48P2
MW:	734.89
EINECS:	681-146-8
Product Categories:	BINAP Series;Chiral Phosphine
Mol File:	135139-00-3.mol

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Chemical Properties

Melting point	203-206°C
alpha	-172 º (c=1 in chloroform)
Boiling point	825.3±65.0 °C(Predicted)
storage temp.	Inert atmosphere,Room Temperature
Water Solubility	Insoluble in water
form	crystal
color	white to pale yellow

Safety Information

Risk Statements	36/37/38
Safety Statements	26-37
TSCA	No

MSDS Information

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Usage And Synthesis

Reaction

Ligand used in copper-catalyzed asymmetric Mannich-type reactions of N-acylimino esters.
Ligand used in the enantioselective fluorination of oxindoles.
Ligand used in [2+2+2] cycloaddition of tetraynes and hexaynes.
Ligand used in the asymmetric reduction of ketone via ruthenium-catalyzed transfer hydrogenation.
Asymmetric hydroboration of unsaturated imines.

Uses

Catalyst for:

Asymmetric hydrogenation of benzophenone
Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives in the presence of chiral biaryl bisphosphine ligands
Regiodivergent rhodium-catalyzed [(2+2)+2] carbocyclization of 1,6-enynes with Me propiolates
Ligand controlled regioselective and stereoselective desymmetrizing rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates with arylboronic acids to form regioisomeric arylcyclopentenols
Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature
Stereoselective preparation of chiral N,O-biaryls via Rh-catalyzed [2+2+2] cycloaddition of conjugate ynamides with diynes

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl Preparation Products And Raw materials

Welcome！

Please leave a message for us or use the following ways to contact us, we will reply to you as soon as possible, and provide you with the most sincere service, thank you.

NO. 18 ,Wujiang Road, Wulidian Street, Jiangbei District, Chongqing
+86-23-6139-8061 +86-13650506873
danny@chemdad.com sales@chemdad.com
www.chemdad.com
WhatsApp +86-13650506873