Product

4-Bromo-1,2-(methylenedioxy)benzene

CAS No.：2635-13-4

Other grades of this product :

4-Bromo-1,2-(methylenedioxy)benzene Basic information

Product Name:	4-Bromo-1,2-(methylenedioxy)benzene
Synonyms:	5-bromobenzo[d][1,3]dioxole;4-BROMO-1,2-(METHYLENEDIOXY)ENZENE;4-Bromo-1,2-methylenedioxybenzene 99%;5-Bromo-1,3-benzodioxole 99%;BROMOBENZODIOXOLE;4-Bromo-1,2-(methylenedioxy)benzene-5;1-Bromo-3,4-(methylenedioxy)benzene 97%;5-Bromo-1,3-benzodioxolane
CAS:	2635-13-4
MF:	C7H5BrO2
MW:	201.02
EINECS:	220-123-5
Product Categories:	Building Blocks;Chemical Synthesis;Miscellaneous;Organic Building Blocks;Oxygen Compounds;Protected Alcohols/Phenols;Aromatic Hydrocarbons (substituted) & Derivatives;Bromine Compounds;Miscellaneous Compounds
Mol File:	2635-13-4.mol

4-Bromo-1,2-(methylenedioxy)benzene Chemical Properties

Boiling point	85-86 °C1 mm Hg(lit.)
density	1.669 g/mL at 25 °C(lit.)
refractive index	n20/D 1.583(lit.)
Fp	>230 °F
storage temp.	Inert atmosphere,Room Temperature
solubility	Chloroform, Methanol (Sparingly)
form	Liquid
Specific Gravity	1.669
color	Clear yellow-orange
BRN	127407
Stability:	Light Sensitive
InChIKey	FBOYMIDCHINJKC-UHFFFAOYSA-N
CAS DataBase Reference	2635-13-4(CAS DataBase Reference)
NIST Chemistry Reference	4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36-37/39
WGK Germany	3
Hazard Note	Irritant
HS Code	29329990

MSDS Information

Provider	Language
4-Bromo-1,2-(methylenedioxy)benzene	English
ACROS	English
SigmaAldrich	English
ALFA	English

4-Bromo-1,2-(methylenedioxy)benzene Usage And Synthesis

Chemical Properties	clear yellow-orange liquid
Synthesis Reference(s)	Tetrahedron, 64, p. 4999, 2008 DOI: 10.1016/j.tet.2008.03.085
General Description	The coupling of 1-bromo-3,4-(methylenedioxy)benzene with β-methallyl alcohol was catalyzed by Pd(OAc)₂ in combination with P(t-Bu)₃.

4-Bromo-1,2-(methylenedioxy)benzene Preparation Products And Raw materials

Preparation Products

3,4-METHYLENEDIOXYPHENYLBORONIC ACID-->PIPERONALDOXIME-->1-IODO-3,4-METHYLENEDIOXYBENZENE

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