METHYL PHENYLPROPIOLATE

METHYL PHENYLPROPIOLATE
  • CAS No.:4891-38-7
Other grades of this product :
METHYL PHENYLPROPIOLATE Basic information
Product Name:METHYL PHENYLPROPIOLATE
Synonyms:METHYL-(PHENYLPROPIOLAT);METHYL PHENYLPROPIOLATE;METHYL 3-PHENYLPROPIOLATE;2-Phenyl-1-carbomethoxyacetylene;2-Propynoic acid, 3-phenyl-, methyl ester;Methyl 3-phenyl-2-propynoate;Methyl 3-phenylpropynoate;Methyl phenylacetylenecarboxylate
CAS:4891-38-7
MF:C10H8O2
MW:160.17
EINECS:
Product Categories:C10 to C11;Carbonyl Compounds;Esters
Mol File:4891-38-7.mol
METHYL PHENYLPROPIOLATE Chemical Properties
Melting point 26°C
Boiling point 109-112 °C/2 mmHg (lit.)
density 1.086 g/mL at 25 °C (lit.)
refractive index n20/D 1.5590(lit.)
Fp >230 °F
storage temp. Inert atmosphere,Room Temperature
form Liquid After Melting
color Clear colorless to pale yellow
BRN 472813
InChIKeyJFGWPXKGINUNDH-UHFFFAOYSA-N
CAS DataBase Reference4891-38-7(CAS DataBase Reference)
Safety Information
Hazard Codes Xi
Risk Statements 36/38
Safety Statements 26-36
WGK Germany 3
HS Code 29163900
MSDS Information
ProviderLanguage
SigmaAldrich English
ACROS English
ALFA English
METHYL PHENYLPROPIOLATE Usage And Synthesis
Chemical Propertiesclear colorless to pale yellow liquid
UsesMethyl phenylpropiolate may be used in the synthesis of:
  • bicyclohexadienes
  • cis-methyl cinnamate
  • (E)-alkyl 3-(dialkoxyphosphoryl)-3-phenylacrylate derivatives
Synthesis Reference(s)The Journal of Organic Chemistry, 52, p. 4859, 1987 DOI: 10.1021/jo00231a007Tetrahedron Letters, 21, p. 849, 1980 DOI: 10.1016/S0040-4039(00)71522-X
General DescriptionOrganoiron carbonyl complexes are obtained by reacting methyl phenylpropiolate with Fe2(CO)9.
METHYL PHENYLPROPIOLATE Preparation Products And Raw materials
Preparation ProductsP-NITROPHENYL PHOSPHATE

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