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| 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Basic information |
| Product Name: | 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE | | Synonyms: | TRISYLHYDRAZIDE;TPSH;TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE;2,4,6-triisopropylbenzenesulphonohydrazide;2,4,6-Triisopropyl benzenesulphonohydrazine;2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE;2,4,6-TRIISOPROPYL BENZENESULFONYL HYDRAZINE;2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE | | CAS: | 39085-59-1 | | MF: | C15H26N2O2S | | MW: | 298.44 | | EINECS: | 254-282-7 | | Product Categories: | Building Blocks;Chemical Synthesis;Organic Building Blocks;Sulfonyl Hydrazides;Sulfur Compounds | | Mol File: | 39085-59-1.mol |
| 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemical Properties |
| Melting point | 110-112 °C (dec.) (lit.) | | Boiling point | 396.6±52.0 °C(Predicted) | | density | 1.075 | | storage temp. | -20°C | | solubility | Chloroform (Slightly), Methanol (Slightly) | | pka | 9.51±0.10(Predicted) | | form | Solid | | color | Off-White | | Sensitive | Moisture Sensitive | | BRN | 2145001 | | InChIKey | GBQCDUBJTLROBV-UHFFFAOYSA-N | | CAS DataBase Reference | 39085-59-1(CAS DataBase Reference) |
| Hazard Codes | Xi | | Safety Statements | 22-24/25 | | RIDADR | UN 1325 4.1/PG III | | WGK Germany | 3 | | F | 4.8-10 | | HazardClass | 4.1 | | PackingGroup | III | | HS Code | 29350090 |
| 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Usage And Synthesis |
| Chemical Properties | White crystal | | Uses | As a reagent for generation of diimide | | Uses | 2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.It can be used as a reagent to synthesize: - Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
- Vinyl sulfones by sulfonylation reaction of vinyl bromides.
- Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.
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| 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Preparation Products And Raw materials |
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