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| CHLOROMETHYL PHENYL SULFIDE Basic information |
| CHLOROMETHYL PHENYL SULFIDE Chemical Properties |
| Boiling point | 66 °C/0.2 mmHg (lit.) | | density | 1.184 g/mL at 25 °C (lit.) | | refractive index | n20/D 1.594(lit.) | | Fp | 214 °F | | storage temp. | 2-8°C | | form | Liquid | | color | Clear colorless to pale yellow | | Sensitive | Stench | | BRN | 1617369 | | InChIKey | LLSMWLJPWFSMCP-UHFFFAOYSA-N | | CAS DataBase Reference | 7205-91-6(CAS DataBase Reference) |
| Safety Statements | 23-24/25 | | RIDADR | UN 3334 | | WGK Germany | 3 | | F | 10-13 | | Hazard Note | Stench | | HazardClass | 4.1 | | PackingGroup | III | | HS Code | 29309099 |
| CHLOROMETHYL PHENYL SULFIDE Usage And Synthesis |
| Uses | Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters.1 | | Uses | Reagent for the high-yield thiomethylation of O-silylated lactone and ester enolates in the synthesis of α-methylene lactones and esters. | | Purification Methods | Dissolve the sulfide in CH2Cl2 or CCl4 and dry it (CaCl2), or pass it through a tube of CaCl2 and distil it using a fractionating column. Harmful vapours. It gives the sulfone [7205-98-3] (b 130o/1mm and m 53o from EtOH) [Beilstein 6 IV 1507] on oxidation with permonophthalic acid. [B.hme et al. Justus Liebigs Ann Chem 563 54 64 1949.] [Beilstein 6 III 1002.] |
| CHLOROMETHYL PHENYL SULFIDE Preparation Products And Raw materials |
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