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| (S)-(-)-METHYL P-TOLYL SULFOXIDE Basic information |
| (S)-(-)-METHYL P-TOLYL SULFOXIDE Chemical Properties |
| Melting point | 75-77 °C(lit.) | | Boiling point | 282.4±19.0 °C(Predicted) | | density | 1.15±0.1 g/cm3(Predicted) | | optical activity | [α]20/D 145°, c = 2 in acetone | | BRN | 2324696 |
| (S)-(-)-METHYL P-TOLYL SULFOXIDE Usage And Synthesis |
| Uses | (S)-(-)-Methyl p-tolyl sulfoxide can be used as a nucleophilic reagent to synthesize: - Optically active β-disulfoxides by reacting with arenesulfinic esters via formation of α-sulfinylcarbanion.
- α-substituted N-hydroxylamines by treating with nitrones via preparation of (S)-(-)-methyl p-tolyl sulfoxide anion.
- 2-O-benzyl-3,4-O-isopropylidene-L-erythrose by one-carbon homologation of 2,3-O-isopropylidene-L-glyceraldehyde.
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| (S)-(-)-METHYL P-TOLYL SULFOXIDE Preparation Products And Raw materials |
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