ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER

ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER
  • CAS No.:60456-21-5
Other grades of this product :
ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER Basic information
Product Name:ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER
Synonyms:(S)-2,2-Dimethyl-[1,3]dioxcdane-4-carboxylic acid methyl ester;METHYL 2,3-O-ISOPROPYLIDENE-L-GLYCERATE;METHYL ALPHA, BETA-ISOPROPYLIDENE-L-GLYCERATE;METHYL (S)-(-)2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXYLATE;METHYL (S)-2,2-DIMETHYL-1,3-DIOXOLANE-4-CARBOXYLATE;ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER;α,β-isopropylidene-l-glyceric acid methyl ester;(S)-2,2-Dimethyl-[1,3]dioxolane-4-carboxylic acid methyl ester
CAS:60456-21-5
MF:C7H12O4
MW:160.17
EINECS:
Product Categories:pharmacetical
Mol File:60456-21-5.mol
ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER Chemical Properties
Boiling point 84-86 °C/15 mmHg (lit.)
density 1.106 g/mL at 25 °C (lit.)
refractive index n20/D 1.425(lit.)
Fp 78°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
optical activity[α]20/D 8.5°, c = 1.5 in acetone
BRN 4292352
InChIKeyDOWWCCDWPKGNGX-YFKPBYRVSA-N
Safety Information
Safety Statements 23-24/25
WGK Germany 3
10-23
HS Code 2932990090
MSDS Information
ProviderLanguage
SigmaAldrich English
ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER Usage And Synthesis
Uses(?)-Methyl (S)-2,2-dimethyl-1,3-dioxolane-4-carboxylate can be used:
  • As a chiral building block to make the key tetrahydrofuran subunit of (?)-gymnodimine, a marine algal toxin.
  • To prepare an enedione by reacting with dimethyl methylphosphonate, BuLi, and phenylglyoxal, which in turn is used to synthesize cyclopentenone derivatives.
  • As a starting material for the preparation of (S)-4,5-dihydroxy-2,3-pentanedione (DPD), a precursor for autoinducer (AI)-2 in bacteria.
ALPHA,BETA-ISOPROPYLIDENE-L-GLYCERIC ACID METHYL ESTER Preparation Products And Raw materials
Preparation Products(S)-methyl 2,3-dihydroxypropanoate

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