Coumalic acid

Coumalic acid
  • CAS No.:500-05-0
Other grades of this product :
Coumalic acid Basic information
Product Name:Coumalic acid
Synonyms:2-Oxo-2H-pyran-5-carboxylic acid, 2-Pyrone-5-carboxylic acid;6-Oxopyran-3-carboxylic acid;a-Pyrone-5-carboxylic acid;α-Pyrone-5-carboxylic acid;Coumalic acid, 5-Carboxy-2-pyrone;courMaric acid;2H-Pyran-5-carboxylic acid, 2-oxo;CouMalic acid 97%
CAS:500-05-0
MF:C6H4O4
MW:140.09
EINECS:207-899-0
Product Categories:sy
Mol File:500-05-0.mol
Coumalic acid Chemical Properties
Melting point 203-205 °C (dec.) (lit.)
Boiling point 218 °C/120 mmHg (lit.)
density 1.2154 (rough estimate)
refractive index 1.4434 (estimate)
Fp 218°C/120mm
storage temp. Sealed in dry,Room Temperature
pka2.80±0.20(Predicted)
form powder to crystal
color White to Light yellow to Light orange
Water Solubility Very soluble in water.
Merck 14,2557
BRN 119747
CAS DataBase Reference500-05-0(CAS DataBase Reference)
NIST Chemistry Reference2H-Pyran-5-carboxylic acid, 2-oxo-(500-05-0)
EPA Substance Registry System2H-Pyran-5-carboxylic acid, 2-oxo- (500-05-0)
Safety Information
Hazard Codes Xi
Safety Statements 22-24/25
WGK Germany 3
TSCA Yes
HS Code 29322090
MSDS Information
ProviderLanguage
2-Oxo-2H-pyran-5-carboxylic acid English
ACROS English
SigmaAldrich English
ALFA English
Coumalic acid Usage And Synthesis
Chemical Propertiespale yellow to pale brown powder
UsesCoumalic acid undergoes thermal reaction with 1,3-butadiene to yield dimethyl tricycle[3.2.1.02,7]oct-3-ene-2,4-dicarboxylate.
General DescriptionDecarboxylates to α-pyrone, a Diels-Alder diene.
Purification MethodsThe acid crystallises from MeOH. The methyl ester has m 73-74o (from pet ether) and b 178-180o/60 mm. [Beilstein 18/8 V 120.]

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