| TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Basic information |
| Product Name: | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE |
| Synonyms: | TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE;(trimethylsilyl)methylmagnesium chl. sol;Trimethylsilylmethylmagnesium chloride (20% in ethyl ether;(TRIMETHYLSILYLMETHYL)MAGNESIUM CHLORIDE , 1.0M SOLUTION IN DIETHYL ETHER;(TRIMETHYLSILYL)METHYLMAGNESIUM CHL. SOL , 1 M IN DIETH.ETHER;[(Trimethylsilyl)methyl]magnesium Chloride 1.0 M In Diethyl Ether;[(Trimethylsilyl)methyl]magnesium Chloride, 1.0 M In Tetrahydrofuran;(Trimethylsilyl)methylmagnesium chloride, 1.1M solution in THF |
| CAS: | 13170-43-9 |
| MF: | C4H11ClMgSi |
| MW: | 146.97 |
| EINECS: | |
| Product Categories: | Si (Classes of Silicon Compounds);Si-(C)4 Compounds;Silicon Compounds (for Synthesis);Synthetic Organic Chemistry;Typical Metal Compounds;Alkyl;Classes of Metal Compounds;Grignard Reagents;Grignard Reagents & Alkyl Metals;Mg (Magnesium) Compounds;Grignard Reagents;Organometallic Reagents |
| Mol File: | 13170-43-9.mol |
| TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Chemical Properties |
| Melting point | 105.8-106.4 °C |
| density | 1.04 |
| Fp | -40°C |
| storage temp. | Flammables + water-Freezer (-20°C)e area |
| solubility | Sol ethereal solvents; reacts with protic solvents. |
| form | Low Melting Solid |
| Specific Gravity | 0.912 |
| color | Clear colorless to yellow to greenish |
| Hydrolytic Sensitivity | 8: reacts rapidly with moisture, water, protic solvents |
| Sensitive | Air & Moisture Sensitive |
| BRN | 3587255 |
| CAS DataBase Reference | 13170-43-9(CAS DataBase Reference) |
| Safety Information |
| Hazard Codes | F+,C,F |
| Risk Statements | 12-14-22-34-66-67-19-11 |
| Safety Statements | 16-26-36/37/39-43-45 |
| RIDADR | UN 3399 4.3/PG 1 |
| WGK Germany | 1 |
| F | 10 |
| TSCA | No |
| HazardClass | 8 |
| PackingGroup | II |
| HS Code | 29319090 |
| MSDS Information |
| Provider | Language |
|---|---|
| ACROS | English |
| SigmaAldrich | English |
| TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Usage And Synthesis |
| Chemical Properties | Grey liquid |
| Uses | Trimethylsilylmethylmagnesium Chloride is used in the methylenation of carbonyl compounds; provides a variety of methods to prepare allylsilanes.It participates in the reactions of Peterson Alkenation, Reaction with Carboxylic Acid Derivatives, Reaction with Alkyl Halides, Reaction with Sulfur Compounds, Reaction with Other Electrophiles, Cross-coupling Reactions, Carbometalation, and as a Generator of Alkyl Radicals from Alkyl Halides in the Presence of Cobalt Catalysts etc. |
| Uses | Reagent used in a variety of nickel catalyzed reactions including alkenation of dithioacetals, cross-coupling with aryl triflates and carbamates, and cross-coupling with vinyl selenides. |
| Preparation | From (chloromethyl)trimethylsilane and magnesium in an ethereal solvent. |
| TRIMETHYLSILYLMETHYLMAGNESIUM CHLORIDE Preparation Products And Raw materials |
| Raw materials | Diethyl ether-->Magnesium-->Chloromethyltrimethylsilane |
| Preparation Products | Cyclohexene, 2-ethenyl-1,3,3-trimethyl--->3-methylideneoxetane |
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