Product

3-Bromo-2-pyridinamine

CAS No.：13534-99-1

Other grades of this product :

3-Bromo-2-pyridinamine Basic information

Product Name:	3-Bromo-2-pyridinamine
Synonyms:	3-BROMO-2-PYRIDINAMINE;3-BROMOPYRIDIN-2-AMINE;3-BROMO-PYRIDIN-2-YLAMINE;2-AMINO-3-BROMOPYRIDINE;IFLAB-BB F1371-0194;2-Pyridinamine, 3-bromo-;TIMTEC-BB SBB005538;2-AMINO-3-BROMOPYRIDINE 97%
CAS:	13534-99-1
MF:	C5H5BrN2
MW:	173.01
EINECS:	629-620-5
Product Categories:	Boronic Acid;C5Heterocyclic Building Blocks;Pyridine;pharmacetical;Halogenated Heterocycles;Heterocyclic Building Blocks;Pyridine series;Pyridines
Mol File:	13534-99-1.mol

3-Bromo-2-pyridinamine Chemical Properties

Melting point	63-67 °C
Boiling point	232.0±20.0 °C(Predicted)
density	1.6065 (rough estimate)
vapor pressure	0.83-1.8Pa at 20-25℃
refractive index	1.5182 (estimate)
storage temp.	Keep in dark place,Inert atmosphere,Room temperature
form	Powder
pka	4.14±0.36(Predicted)
color	Gray to brown
BRN	109867
LogP	1.5 at 20℃ and pH7
CAS DataBase Reference	13534-99-1(CAS DataBase Reference)

Safety Information

Hazard Codes	Xi
Risk Statements	36/37/38
Safety Statements	26-36
WGK Germany	3
HazardClass	IRRITANT
PackingGroup	II
HS Code	29333990

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

3-Bromo-2-pyridinamine Usage And Synthesis

Chemical Properties

grey to brown powder

Uses

2-Amino-3-bromopyridine may be used to synthesize:

2-acylamido-3-bromopyridines
2-anilino-3-bromopyridine
3-[(2-methoxyphenyl)ethynyl]pyridin-2-amine
3-[(4-methoxyphenyl)ethynyl]pyridin-2-amine
N-(bromopyridyl)amidines
carbolines via palladium catalyzed arylation followed by palladium catalyzed amination reaction
2-amino-3-cyanopyridine via palladium catalyzed cyanation reaction with potassium ferro-cyanide in the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene [DBU]
nitro-substituted N,N′-dipyridinylamines via palladium catalyzed coupling reaction with 2-chloro-3-nitropyridine in the presence of Xantphos ligand
2-amino-3-iodopyridine via reaction with sodium iodide in the presence of copper(I)iodide and trans-N,N′-dimethylcyclohexane-1,2-diamine

3-Bromo-2-pyridinamine Preparation Products And Raw materials

Preparation Products

3-BROMO-5-IODOPYRIDIN-2-AMINE-->3-Bromo-2-hydroxypyridine-->3-Iodopyridin-2-amine

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