(R,R)-(+)-HYDROBENZOIN
(R,R)-(+)-HYDROBENZOIN
  • CAS No.:52340-78-0
Other grades of this product :
(R,R)-(+)-HYDROBENZOIN Basic information
Product Name:(R,R)-(+)-HYDROBENZOIN
Synonyms:(1R,2R)-(+)-HYDROBENZOIN;(1R,2R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIOL;(R,R)-(+)-HYDROBENZOIN;(R,R)-(+)-1,2-DIPHENYL-1,2-ETHANEDIOL;(R,R)-1,2-DIPHENYL-1,2-ETHANEDIOL;(R,R)-(+)-1,2-DIPHENYLETHANEDIOL;(R,R)-1,2-DIPHENYL-ETHYLENE GLYCOL;(R,R)-(+)-HYDROBENZOIN, 99% (99% EE/HPL&
CAS:52340-78-0
MF:C14H14O2
MW:214.26
EINECS:
Product Categories:
Mol File:52340-78-0.mol
(R,R)-(+)-HYDROBENZOIN Chemical Properties
Melting point 146-149 °C(lit.)
Boiling point 314.4°C (rough estimate)
density 1.0781 (rough estimate)
refractive index 95 ° (C=1, CHCl3)
storage temp. Sealed in dry,Room Temperature
form Crystalline Powder or Crystals
pka13.38±0.20(Predicted)
color White to beige or light brown
optical activity[α]28/D +93°, c = 2.5 in ethanol
Merck 14,4777
BRN 2050815
CAS DataBase Reference52340-78-0(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
10
HS Code 29062990
MSDS Information
ProviderLanguage
ACROS English
SigmaAldrich English
ALFA English
(R,R)-(+)-HYDROBENZOIN Usage And Synthesis
Chemical Propertieswhite to beige or light brown crystalline powder
Uses(R,R)-(+)-Hydrobenzoin may be used in the oxyselenenylation step in the multi-step synthesis of cyclopentitols and aminocyclopentitols from cyclopentene. It may also be used as a ligand for the asymmetric addition of diethylzinc to aldehydes in the presence or absence of titanium tetra-isopropoxide to form (R)- or (S)-form of the corresponding secondary alcohol, respectively.
General Description(R,R)-(+)-Hydrobenzoin is a chiral 1,2-diol useful as a chiral reagent, building block, ligand or auxiliary in asymmetric synthesis.
(R,R)-(+)-HYDROBENZOIN Preparation Products And Raw materials
Raw materialstert-Butanol-->4-Methylmorpholine N-oxide monohydrate-->TRANS-STILBENE-->Tiron-->Potassium osmate(VI) dihydrate-->(DHQ)2PHAL
Preparation ProductsPhenylacetic acid

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