(S)-Xyl-SDP

(S)-Xyl-SDP
  • CAS No.:528521-89-3
Other grades of this product :
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Basic information
Reaction
Product Name:(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
Synonyms:(S)-7,7-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1-SPIROBIINDANE;(S)-7,7'-Bis[di(3,5-dimethylphenyl)phosphino]-1,1'-spirobiindane ,97%;(S)-()-7,7′-Bis[di(3,5-dimethylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobiindene;(S)–7,7′-Bis[di(3,5-dimethylphenyl)phosphino]-1,1′-spirobiindan;1,1'-[(1S)-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBI[1H-INDENE]-7,7'-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)PHOSPHINE];1,1'-[(1S)-2,2',3,3'-Tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl]bis[1,1-bis(3,5-dimethylphenyl)phosphine],99%e.e.;(R)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-SPIROBIINDANE;(R)-(+)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE
CAS:528521-89-3
MF:C49H50P2
MW:700.87
EINECS:
Product Categories:BINAP Series;Chiral Phosphine;Chiral Spiro Ligand
Mol File:528521-89-3.mol
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Chemical Properties
Melting point >300°C
alpha -83° (c 0.53, CH2Cl2)
Boiling point 794.8±60.0 °C(Predicted)
storage temp. -20°C
form solid
color off-white to pale yellow
optical activity[α]22/D 62.0°, c = 1 in chloroform
Sensitive air sensitive
InChIKeyAZSBNBQMIMQOPG-UHFFFAOYSA-N
CAS DataBase Reference528521-89-3
Safety Information
WGK Germany 3
HS Code 29319090
MSDS Information
(S)-(-)-7,7'-BIS[DI(3,5-DIMETHYLPHENYL)PHOSPHINO]-2,2',3,3'-TETRAHYDRO-1,1'-SPIROBIINDANE Usage And Synthesis
Reaction
  1. Chiral ligands for ruthenium-catalyzed asymmetric hydrogenation of simple ketones.
  2. Chiral ligands for ruthenium-catalyzed asymmetric hydrogenation of racemic α-aryl cyclic ketones via dynamic kinetic resolution. 
Chemical PropertiesColorless oil

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