| 4-(Dimethylamino)benzophenone Basic information |
| Product Name: | 4-(Dimethylamino)benzophenone |
| Synonyms: | (4-Dimethylamino-phenyl)-phenyl-methanone;[4-(Dimethylamino)phenyl](phenyl)methanone;[4-(dimethylamino)phenyl]phenyl-methanon;[4-(Dimethylamino)phenyl]phenylmethanone;4-Dimethylaminobenzophenon;Benzenamine,N,N-dimethyl-4-(phenylmethanone)-;Benzophenone, 4-(dimethylamino)-;Methanone,[4-(dimethylamino)phenyl]phenyl- |
| CAS: | 530-44-9 |
| MF: | C15H15NO |
| MW: | 225.29 |
| EINECS: | 208-478-4 |
| Product Categories: | Aromatic Benzophenones & Derivatives (substituted);Amine Photochemical CoinitiatorsPolymerization Initiators;Benzophenone;Organic Photoinitiators;Polymer Science;Polymerization Initiators |
| Mol File: | 530-44-9.mol |
| 4-(Dimethylamino)benzophenone Chemical Properties |
| Melting point | 88-90 °C(lit.) |
| Boiling point | 250 °C / 15mmHg |
| density | 1.0463 (rough estimate) |
| refractive index | 1.5200 (estimate) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| form | powder to crystal |
| pka | 2.12±0.12(Predicted) |
| color | White to Light yellow to Green |
| Water Solubility | insoluble |
| Merck | 14,3233 |
| InChIKey | BEUGBYXJXMVRFO-UHFFFAOYSA-N |
| CAS DataBase Reference | 530-44-9(CAS DataBase Reference) |
| NIST Chemistry Reference | Methanone, [4-(dimethylamino)phenyl]phenyl-(530-44-9) |
| EPA Substance Registry System | Methanone, [4-(dimethylamino)phenyl]phenyl- (530-44-9) |
| Safety Information |
| Hazard Codes | Xi |
| Risk Statements | 36/37/38 |
| Safety Statements | 26-37/39 |
| WGK Germany | 3 |
| TSCA | Yes |
| HS Code | 29223900 |
| MSDS Information |
| Provider | Language |
|---|---|
| 4-(Dimethylamino)benzophenone | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 4-(Dimethylamino)benzophenone Usage And Synthesis |
| Chemical Properties | YELLOW CRYSTALLINE POWDER OR CRYSTALS |
| Uses | 4-(Dimethylamino)benzophenone is an important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field. |
| Synthesis Reference(s) | Synthesis, p. 544, 1986 DOI: 10.1055/s-1986-31696Tetrahedron Letters, 34, p. 7595, 1993 DOI: 10.1016/S0040-4039(00)60409-4 |
| Purification Methods | Crystallise the pale green p-dimethylaminobenzophenone from EtOH. Dissolve 100g in 600mL of boiling EtOH, add 5g of charcoal, cool, isolate the solid by centrifugation and similarly wash the pale crystals with ice-cold EtOH. When filtered by suction, EtOH solution remains on the crystals and turns deep green in air. Dry it in a vacuum and store it in the dark. The hydrazone has m 128-130o and forms a ketyl with potassium. [Hurd & Webb Org Synth Coll Vol I 217 1941, Beilstein 14 H 82, 14 I 288, 14 III 218, 14 IV 248.] |
| 4-(Dimethylamino)benzophenone Preparation Products And Raw materials |
| Raw materials | Phosphorus oxychloride-->N-Methylaniline-->BENZANILIDE |
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