4-(Dimethylamino)benzophenone

4-(Dimethylamino)benzophenone
  • CAS No.:530-44-9
Other grades of this product :
4-(Dimethylamino)benzophenone Basic information
Product Name:4-(Dimethylamino)benzophenone
Synonyms:(4-Dimethylamino-phenyl)-phenyl-methanone;[4-(Dimethylamino)phenyl](phenyl)methanone;[4-(dimethylamino)phenyl]phenyl-methanon;[4-(Dimethylamino)phenyl]phenylmethanone;4-Dimethylaminobenzophenon;Benzenamine,N,N-dimethyl-4-(phenylmethanone)-;Benzophenone, 4-(dimethylamino)-;Methanone,[4-(dimethylamino)phenyl]phenyl-
CAS:530-44-9
MF:C15H15NO
MW:225.29
EINECS:208-478-4
Product Categories:Aromatic Benzophenones & Derivatives (substituted);Amine Photochemical CoinitiatorsPolymerization Initiators;Benzophenone;Organic Photoinitiators;Polymer Science;Polymerization Initiators
Mol File:530-44-9.mol
4-(Dimethylamino)benzophenone Chemical Properties
Melting point 88-90 °C(lit.)
Boiling point 250 °C / 15mmHg
density 1.0463 (rough estimate)
refractive index 1.5200 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform (Slightly), Methanol (Slightly)
form powder to crystal
pka2.12±0.12(Predicted)
color White to Light yellow to Green
Water Solubility insoluble
Merck 14,3233
InChIKeyBEUGBYXJXMVRFO-UHFFFAOYSA-N
CAS DataBase Reference530-44-9(CAS DataBase Reference)
NIST Chemistry ReferenceMethanone, [4-(dimethylamino)phenyl]phenyl-(530-44-9)
EPA Substance Registry SystemMethanone, [4-(dimethylamino)phenyl]phenyl- (530-44-9)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
TSCA Yes
HS Code 29223900
MSDS Information
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4-(Dimethylamino)benzophenone Usage And Synthesis
Chemical PropertiesYELLOW CRYSTALLINE POWDER OR CRYSTALS
Uses4-(Dimethylamino)benzophenone is an important organic intermediate. It can be used in agrochemical, pharmaceutical and dyestuff field.
Synthesis Reference(s)Synthesis, p. 544, 1986 DOI: 10.1055/s-1986-31696Tetrahedron Letters, 34, p. 7595, 1993 DOI: 10.1016/S0040-4039(00)60409-4
Purification MethodsCrystallise the pale green p-dimethylaminobenzophenone from EtOH. Dissolve 100g in 600mL of boiling EtOH, add 5g of charcoal, cool, isolate the solid by centrifugation and similarly wash the pale crystals with ice-cold EtOH. When filtered by suction, EtOH solution remains on the crystals and turns deep green in air. Dry it in a vacuum and store it in the dark. The hydrazone has m 128-130o and forms a ketyl with potassium. [Hurd & Webb Org Synth Coll Vol I 217 1941, Beilstein 14 H 82, 14 I 288, 14 III 218, 14 IV 248.]
4-(Dimethylamino)benzophenone Preparation Products And Raw materials
Raw materialsPhosphorus oxychloride-->N-Methylaniline-->BENZANILIDE

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