O-DIPHENYLPHOSPHINYLHYDROXYLAMINE

O-DIPHENYLPHOSPHINYLHYDROXYLAMINE
  • CAS No.:72804-96-7
Other grades of this product :
O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Basic information
Product Name:O-DIPHENYLPHOSPHINYLHYDROXYLAMINE
Synonyms:O-DIPHENYLPHOSPHINYLHYDROXYLAMINE;O-(diphenylphosphoryl)hydroxylaMine;TwoPhenylphosphonichydroxylaMine;diphenylphosphinate;O-(Diphenylphosphinyl)hydroxylamine;aMino diphenylphosphinate;(AMinooxy)diphenylphosphine oxide;HydroxylaMine, O-(diphenylphosphinyl)-
CAS:72804-96-7
MF:C12H12NO2P
MW:233.2
EINECS:
Product Categories:
Mol File:72804-96-7.mol
O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Chemical Properties
Melting point >140℃ (decomposition)
Boiling point 368.0±25.0 °C(Predicted)
density 1.25±0.1 g/cm3(Predicted)
storage temp. 2-8°C
solubility DMSO (Slightly), Methanol (Very Slightly, Sonicated)
form solid
pka-1.65±0.70(Predicted)
color white
Safety Information
WGK Germany 3
MSDS Information
O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Usage And Synthesis
Chemical PropertiesLight yellow or white powder solid
UsesEfficient reagent for direct conversion of aldehydes to nitriles in the presence of alcohol, ketone, ester, or amine functionality.
UsesO-Diphenylphosphinylhydroxylamine is a versatile reactant used in the synthetic preparation of various products such as trans-acylaziridines and aldohydrazones.
Synthesis Reference(s)Tetrahedron Letters, 23, p. 3835, 1982 DOI: 10.1016/S0040-4039(00)87720-5
General DescriptionO-(Diphenylphosphinyl)hydroxylamine is a general reagent for electrophilic C-amination, which aminates a variety of stable carbanions and Grignard reagents.
O-DIPHENYLPHOSPHINYLHYDROXYLAMINE Preparation Products And Raw materials
Raw materialsN-hydroxy-P,P-diphenylphosphinic aMide-->Diphenylphosphinyl chloride-->Methyl diphenylphosphinate

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