Product

Allyl chloroformate

CAS No.：2937-50-0

Other grades of this product :

Allyl chloroformate Basic information

Product Name:	Allyl chloroformate
Synonyms:	2-propenylchloroformate;ALLYLCHLOROFORMATE(ACF);Allyl carbonochloridate;Prop-1-enylchlorocarbonate;(Allyloxycarbonyl) chloride;Chloridocarbonic acid allyl;Chloridocarbonic acid allyl ester;Allyl chloroformate,97%
CAS:	2937-50-0
MF:	C4H5ClO2
MW:	120.53
EINECS:	220-916-6
Product Categories:	Amine ProtectionProtection and Derivatization;Others;Pharmaceutical Intermediates;Peptide Synthesis;Protecting and Derivatizing Reagents;Specialty Synthesis;CHLOROFORMATES
Mol File:	2937-50-0.mol

Allyl chloroformate Chemical Properties

Melting point	106℃
Boiling point	109 °C
density	1.134 g/mL at 20 °C(lit.)
vapor pressure	3.67 psi ( 20 °C)
refractive index	n20/D 1.422(lit.)
Fp	88 °F
storage temp.	2-8°C
solubility	Chloroform
form	Liquid
color	Clear slightly yellow to light orange to reddish brown
Odor	Extremely irritating, causes tears; pungent.
BRN	773915
Stability:	Moisture Sensitive
CAS DataBase Reference	2937-50-0(CAS DataBase Reference)
NIST Chemistry Reference	Allyl chloroformate(2937-50-0)
EPA Substance Registry System	Carbonochloridic acid, 2-propen-1-yl ester (2937-50-0)

Safety Information

Hazard Codes	T+
Risk Statements	10-22-26-34
Safety Statements	26-28-36/37/39-45
RIDADR	UN 1722 6.1/PG 1
WGK Germany	3
RTECS	LQ5775000
F	19
HazardClass	6.1(b)
PackingGroup	I
HS Code	29159000
Hazardous Substances Data	2937-50-0(Hazardous Substances Data)

MSDS Information

Provider	Language
Allyl chloroformate	English
SigmaAldrich	English
ACROS	English
ALFA	English

Allyl chloroformate Usage And Synthesis

Chemical Properties	Colorless liquid
Uses	Allyl Chloroformate is used in the synthesis of poly(ethylene oxide) hybrid systems for therapeutic applications and drug delivery. Also used in the synthesis of benzothiazole derivatives with potent anti-tumor properties.
General Description	A colorless liquid with a pungent odor. Flash point 88°F. Corrosive to metals and tissue. Very toxic by inhalation, ingestion and/or skin contact. Vapors are heavier than air.
Air & Water Reactions	Highly flammable. Water reaction produces heat and acidic HCl. In the presence of moist air, corrosive hydrogen chloride is produced.
Reactivity Profile	Acid halides, such as Allyl chloroformate, are water reactive; some are violently reactive. They are incompatible with strong oxidizing agents, alcohols, amines, alkali. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].
Health Hazard	Vapor irritates eyes and respiratory tract. Contact with liquid causes eye and skin irritation, and ingestion irritates mouth and stomach.
Chemical Reactivity	Reactivity with Water Reacts slowly generating hydrogen chloride; Reactivity with Common Materials: Corrosive metals; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Flush with water, rinse with sodium bicarbonate solution; Polymerization: Not pertinent; Inhibitor of Polymerization: Not pertinent.
Safety Profile	Poison by inhalation and ingestion. Corrosive. Dangerous when exposed to heat, open flame (or sparks), or powerful oxidizers. Can react with oxidizing materials. To fight fire, use alcohol foam, spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also ALLYL COMPOUNDS and ESTERS.

Allyl chloroformate Preparation Products And Raw materials

Preparation Products

H-LYS(ALLOC)-OH-->N-alpha-Allyloxycarbonyl-N-epsilon-(9-fluorenylmethyloxycarbonyl)-L-lysine-->ALLYL METHYL ETHER-->Allyl methyl carbonate

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