Borane tert-butylamine complex

CAS No.：7337-45-3

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Borane tert-butylamine complex Basic information

Product Name:	Borane tert-butylamine complex
Synonyms:	TERT-BUTYLAMINE BORANE;tert-butylamine,compd.withbh3(1:1);tert-butylamine,compd.withborane(1:1);trihydro(2-methyl-2-propanamine)-,(T-4)-Boron;BORANE, T-BUTYLAMINE COMPLEX;BORANE-TERT-BUTYLAMINE;BORANE-TERT-BUTYLAMINE COMPLEX;BORON HYDRIDE TERT-BUTYLAMINE
CAS:	7337-45-3
MF:	C4H11BN
MW:	83.94784
EINECS:	230-851-5
Product Categories:	Organometallics;B (Classes of Boron Compounds);Boranes;Reduction;Synthetic Organic Chemistry;organoboron and borato-metal complexes
Mol File:	7337-45-3.mol

Borane tert-butylamine complex Chemical Properties

Melting point	98-100 °C (dec.)(lit.)
density	0,87 g/cm³
storage temp.	Refrigerator
solubility	27g/l
form	powder
color	White to off-white
Water Solubility	Soluble in water (27 g/L at 20°C) and methanol.
BRN	4134905
EPA Substance Registry System	Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- (7337-45-3)

Safety Information

Hazard Codes	T
Risk Statements	21-25-36/37/38
Safety Statements	26-36/37-45
RIDADR	UN 2811 6.1/PG 3
WGK Germany	3
RTECS	EO3900000
F	9
TSCA	Yes
HazardClass	4.1
PackingGroup	III
HS Code	29299090

MSDS Information

Provider	Language
ACROS	English
SigmaAldrich	English
ALFA	English

Borane tert-butylamine complex Usage And Synthesis

Chemical Properties	white to off-white crystalline powder
Uses	Borane-tert-butylamine complex is used in stereoselective reduction of a steroidal ketone and for a review of amine boranes as selective reducing and hydroborating agents. It is also used as strong co-reducing agent in the syntheses of copper (I) oxide nanoparticles, diphosphine-protected gold nanocluster and 4-acetoxycinnamyl alcohols.
Application	Borane tert-butylamine (BTB) complex may be used as strong co-reducing agent in the following syntheses:copper (I) oxide nanoparticlesdiphosphine-protected gold nanocluster4-acetoxycinnamyl alcoholsReactant involved in:Non-destructive analyses and conservation treatments of Indian drawingsDehydrogenation reactions mediated by ruthenium bidentate phosphine complexes or ruthenium / iridium bis(N-heterocyclic carbene) complexesThe formation of σ-borane complexesEthanolysis of amine-borane adducts to form a reducing system for transfer hydrogenation of terminal olefinsPhotochemical hydroboration and oxidation of single-walled carbon nanotubes
General Description	Borane tert-butylamine complex is a mild reducing agent. It participates in the selective reduction of aldehydes and ketones to corresponding alcohol. It takes part as a reducing agent in the synthesis of monodisperse palladium nanoparticles (Pd NPs), monodisperse gold (Au) nanoparticles and carbon-supported Pd electrocatalysts.

Borane tert-butylamine complex Preparation Products And Raw materials

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