5-Amino-1-naphthol

5-Amino-1-naphthol
  • CAS No.:83-55-6
Other grades of this product :
5-Amino-1-naphthol Basic information
Product Name:5-Amino-1-naphthol
Synonyms:1-Naphthalenol, 5-amino-;1-Naphthol, 5-amino-;5-amino-1-naphthaleno;5-Amino-alpha-naphthol;C.I. 76650;5-AMINO-1-NAPHTHOL;5-HYDROXY-1-NAPHTHYLAMINE;1-AMINO-5-HYDROXYNAPHTHALENE
CAS:83-55-6
MF:C10H9NO
MW:159.18
EINECS:201-486-9
Product Categories:Intermediates of Dyes and Pigments;Organic Building Blocks;Oxygen Compounds;Phenols
Mol File:83-55-6.mol
5-Amino-1-naphthol Chemical Properties
Melting point 190 °C (dec.) (lit.)
Boiling point 284.68°C (rough estimate)
density 1.1202 (rough estimate)
refractive index 1.6070 (estimate)
storage temp. -20°C Freezer
solubility DMSO (Slightly), Methanol (Slightly)
pka3.97(at 25℃)
form Solid
color Light Purple to Purple
CAS DataBase Reference83-55-6(CAS DataBase Reference)
NIST Chemistry Reference5-Amino-1-naphthol(83-55-6)
EPA Substance Registry System1-Naphthalenol, 5-amino- (83-55-6)
Safety Information
Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-37/39
WGK Germany 3
HS Code 29222990
MSDS Information
ProviderLanguage
5-Amino-1-naphthol English
ACROS English
SigmaAldrich English
5-Amino-1-naphthol Usage And Synthesis
Chemical Propertiespale purple to brown-purple crystalline powder
Uses5-Amino-1-naphthol is used as a coupling component for azo dyes (coupling takes place ortho to the amino or hydroxyl group, or para to the hydroxyl group depending on the pH), and as an intermediate for sulfur dyes.
Preparation1-Aminonaphthalene-5-sulfonic acid paste (Section 6.2) is added to molten sodium hydroxide at 200°C, and the reaction is completed by heating slowly to 250°C and maintaining this temperature for 3 h. After dilution and careful neutralization with hydrochloric acid, 5-amino-1-naphthol precipitates in 85 % yield (mp 192°C).

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